Identify the specific element that corresponds to each of the following electron configurations and indicate the number of unpaired electrons for each: (a) \(1 s^{2} 2 s^{2},(\mathbf{b}) 1 s^{2} 2 s^{2} 2 p^{4}\) (c) \([\operatorname{Ar}] 4 s^{1} 3 d^{5},(\mathbf{d})[\mathrm{Kr}] 5 s^{2} 4 d^{10} 5 p^{4}\)

Short Answer

Expert verified
a) Beryllium (Be): 0 unpaired electrons b) Oxygen (O): 2 unpaired electrons c) Chromium (Cr): 5 unpaired electrons d) Tellurium (Te): 2 unpaired electrons

Step by step solution

01

Identify element (a)

For the electron configuration \(1s^2 2s^2\), the element has a total of 2 + 2 = 4 electrons, making it element 4 on the periodic table, which is Beryllium (Be).
02

Unpaired electrons (a)

In the case of Beryllium, the electron configuration is complete with no unpaired electrons in the last orbital (2s), so the number of unpaired electrons is 0.
03

Identify element (b)

For the electron configuration \(1s^2 2s^2 2p^4\), the element has a total of 2 + 2 + 4 = 8 electrons, making it element 8 on the periodic table, which is Oxygen (O).
04

Unpaired electrons (b)

In the case of Oxygen, the electron configuration has 4 electrons in the 2p orbital. Since each of the three 2p orbitals can accommodate 2 electrons (one spin up, one spin down), two of the orbitals are filled, and the third orbital has two unpaired electrons.
05

Identify element (c)

For the electron configuration \([\mathrm{Ar}] 4s^1 3d^5\), the element has the electron configuration of Argon plus 1 electron in the 4s orbital and 5 electrons in the 3d orbitals. Argon has an atomic number of 18, so this new element has 18 + 1 + 5 = 24 electrons, making it element 24 on the periodic table, which is Chromium (Cr).
06

Unpaired electrons (c)

In the case of Chromium, the electron configuration ends with 4s and 3d orbitals. The last orbital with unpaired electrons is 3d, which has 5 unpaired electrons.
07

Identify element (d)

For the electron configuration \([\mathrm{Kr}] 5s^2 4d^{10} 5p^{4}\), the element has the electron configuration of Krypton plus 2 electrons in the 5s orbital, 10 electrons in the 4d orbitals, and 4 electrons in the 5p orbitals. Krypton has an atomic number of 36, so this new element has 36 + 2 + 10 + 4 = 52 electrons, making it element 52 on the periodic table, which is Tellurium (Te).
08

Unpaired electrons (d)

In the case of Tellurium, the electron configuration ends with 5p, which has 4 electrons. Since each of the three 5p orbitals can accommodate 2 electrons (one spin up, one spin down), two of the orbitals are filled, and the third orbital has two unpaired electrons. To summarize: a) Beryllium (Be) - 0 unpaired electrons b) Oxygen (O) - 2 unpaired electrons c) Chromium (Cr) - 5 unpaired electrons d) Tellurium (Te) - 2 unpaired electrons

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Unpaired Electrons
Unpaired electrons are those that are alone in an orbital, not forming a pair with another electron with opposite spin. The presence of unpaired electrons is a central concept in chemistry because they are usually the electrons involved in chemical bonding and magnetic properties.

For instance, in the exercise given, Oxygen (O) has two unpaired electrons in its 2p orbitals. This impacts how Oxygen forms bonds with other atoms. Similarly, Chromium (Cr) has five unpaired electrons, which is quite unique and leads to its characteristic magnetic properties and chemical reactivity.

Identifying Unpaired Electrons

When identifying unpaired electrons, one must first understand the Pauli Exclusion Principle, stating that no two electrons in an atom can have identical quantum numbers. Therefore, an orbital can hold two electrons with opposite spins. Using the electron configuration, you can determine which orbitals are not fully occupied and count the unpaired electrons. A filled or half-filled orbital signals stability, while orbitals that are not fully occupied depict the number of unpaired electrons.
Periodic Table
The periodic table is an organized chart of all known elements arranged according to their atomic number, electron configurations, and recurring chemical properties. Each element in the table is represented by its chemical symbol, and the elements are listed in order of increasing atomic number.

Elements in the same column, known as a group, typically have similar properties and electron configurations, especially in their outermost shells. Horizontal rows are called periods and indicate the energy levels of an atom's electrons.

Utilizing the Periodic Table

To solve problems such as determining the element with a given electron configuration, one starts at the top with Hydrogen (atomic number 1) and follows the elements in order until reaching the total number of electrons that matches the configuration. For example, Tellurium (Te), in step 7 of the exercise, can be identified using the periodic table by counting up to atomic number 52.
Atomic Number
The atomic number of an element is the number of protons found in the nucleus of an atom, and it determines the chemical properties and place of an element in the periodic table. Since atoms are electrically neutral, the atomic number also equals the number of electrons in an uncharged atom.

The atomic number is fundamental when working with electron configurations. For example, the number of electrons in a neutral atom will be consistent with its atomic number. The step by step solution identifies elements such as Beryllium (Be) and Chromium (Cr) by matching the total electrons in the electron configuration to the atomic number of the element on the periodic table.

Importance of Knowing the Atomic Number

Understanding the atomic number aids in predicting how an element will react chemically. A lower atomic number typically means the element is more abundant and reactive, while a higher atomic number usually indicates the opposite. For instance, elements with an atomic number greater than 82 (Lead) are all radioactive.

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