The first ionization energy of the oxygen molecule is the energy required for the following process: $$\mathrm{O}_{2}(g) \longrightarrow \mathrm{O}_{2}^{+}(g)+\mathrm{e}^{-}$$ The energy needed for this process is 1175 \(\mathrm{kJ} / \mathrm{mol}\) , very similar to the first ionization energy of \(\mathrm{Xe} .\) Would you expect \(\mathrm{O}_{2}\) to react with \(\mathrm{F}_{2} ?\) If so, suggest a product or products of this reaction.

Short Answer

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In conclusion, it is possible for O₂ to react with F₂ due to the higher reactivity of both the elements, and we can expect the formation of dioxygen difluoride (O₂F₂) as the product of this reaction.

Step by step solution

01

Compare the ionization energies

Given that the first ionization energy for O₂ is 1175 kJ/mol, we can notice that it is very similar to the first ionization energy for Xe. This similarity suggests that O₂ and Xe might have comparable chemical properties and reactivity, which may hint at the possibility of O₂ reacting with F₂.
02

Determine the likelihood of the reaction

As O₂ has a comparable first ionization energy to Xe, and considering that Xe is an inert noble gas and generally does not react with other elements, this makes it less likely for O₂ to react with F₂. However, it is essential to note that O₂ still has a higher reactivity compared to noble gases like Xe due to its double bond character and oxygen's high electronegativity. Also, F₂ is a highly reactive element among halogens. Thus, the chances of O₂ reacting with F₂ cannot be ruled out.
03

Predict the products

Given the possibility of O₂ reacting with F₂, we can predict the products that can form during this process. Oxygen, with an electronegativity of 3.44, doesn't generally form ionic compounds with other non-metals, so we can expect the formation of a covalent compound in this case. The most likely product resulting from the reaction of O₂ and F₂ is dioxygen difluoride, which has the formula O₂F₂. This compound can be formed as follows: \( \mathrm{O}_{2}(g) + 2\,\mathrm{F}_{2}(g) \longrightarrow 2\,\mathrm{O}_{2}\mathrm{F}_{2}(s) \) In conclusion, it is possible for O₂ to react with F₂ due to the higher reactivity of both the elements, and we can expect the formation of dioxygen difluoride (O₂F₂) as the product of this reaction.

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Most popular questions from this chapter

Which element has the highest second ionization energy: Li, K, or Be?

Chlorine reacts with oxygen to form \(\mathrm{Cl}_{2} \mathrm{O}_{7}\) . (a) What is the name of this product (see Table 2.6) ? (b) Write a balanced equation for the formation of \(\mathrm{Cl}_{2} \mathrm{O}_{7}(l)\) from the elements. (c) Would you expect \(\mathrm{Cl}_{2} \mathrm{O}_{7}\) to be more reactive toward \(\mathrm{H}^{+}(a q)\) or \(\mathrm{OH}^{-}(a q) ?(\mathbf{d})\) If the oxygen in \(\mathrm{Cl}_{2} \mathrm{O}_{7}\) is considered to have the \(-2\) oxidation state, what is the oxidation state of the Cl? What is the electron configuration of Cl in this oxidation state?

One way to measure ionization energies is ultraviolet photoelectron spectroscopy (PES), a technique based on the photoelectric efect. (Section 6.2) In PES, monochromatic light is directed onto a sample, causing electrons to be emitted. The kinetic energy of the emitted electrons is measured. The diference between the energy of the photons and the kinetic energy of the electrons corresponds to the energy needed to remove the electrons (that is, the ionization energy). Suppose that a PES experiment is performed in which mercury vapor is irradiated with ultraviolet light of wavelength 58.4 nm. (a) What is the energy of a photon of this light, in joules? (b) Write an equation that shows the process corresponding to the first ionization energy of Hg. (c) The kinetic energy of the emitted electrons is measured to be \(1.72 \times 10^{-18} \mathrm{J} .\) What is the first ionization energy of \(\mathrm{Hg},\) in \(\mathrm{kJ} / \mathrm{mol} ?(\mathbf{d})\) Using Figure \(7.10,\) determine which of the halogen elements has a first ionization energy closest to that of mercury.

Write a balanced equation for the reaction that occurs in each of the following cases: (a) Ozone decomposes to dioxygen. (b) Xenon reacts with fluorine. (Write three different equations.) (c) Sulfur reacts with hydrogen gas. (d) Fluorine reacts with water.

Which neutral atom is isoelectronic with each of the following ions? \(\mathrm{Ga} ^{3+}, \mathrm{Zr}^{4+}, \mathrm{Mn}^{7+}, \mathrm{I}^{-}, \mathrm{Pb}^{2+}.\)

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