(a) What is the trend in electronegativity going from left to right in a row of the periodic table? (b) How do electronegativity values generally vary going down a column in the periodic table? (c) True or false: The most easily ionizable elements are the most electronegative.

Short Answer

Expert verified
(a) Electronegativity increases from left to right across a period in the periodic table due to an increase in the number of protons and a decrease in atomic radius. (b) Electronegativity decreases as we move down a column in the periodic table because of the increase in atomic radius and the electrons being farther away from the nucleus. (c) False. The most easily ionizable elements have low electronegativity as they can readily lose electrons, whereas highly electronegative elements have a greater tendency to attract electrons.

Step by step solution

01

Part (a): Electronegativity trend in a row of the periodic table

Electronegativity generally increases as we move from left to right across a period in the periodic table. This is because the number of protons in the nucleus increases, leading to a stronger positive charge which attracts the electrons more strongly. Additionally, the atomic radius decreases as we move across a period, causing the electrons to be closer to the nucleus. The overall effect is an increase in the tendency to attract a bonding pair of electrons, resulting in a higher electronegativity value.
02

Part (b): Electronegativity trend in a column of the periodic table

As we move down a column or group in the periodic table, electronegativity generally decreases. This occurs because the atomic radius increases as more energy levels are added to the electron configuration. With larger atomic radii, the electrons are farther away from the nucleus and less attracted by the positive charge of the protons. Consequently, the tendency of an atom to attract a bonding pair of electrons is weaker, leading to lower electronegativity values.
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Part (c): Checking the validity of the statement

The statement "The most easily ionizable elements are the most electronegative" is false. In fact, it's quite the opposite. The most easily ionizable elements are those with low electronegativity. When an element is easily ionizable, it means that it has a low ionization energy and can readily lose electrons to form a positive ion (cation). On the other hand, highly electronegative elements have a greater tendency to attract electrons and generally do not lose electrons easily. To further support this claim, consider that the most easily ionizable elements are usually found in Group 1 (alkali metals) of the periodic table, while the most electronegative elements are found in Group 17 (halogens). So, the statement is incorrect.

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Most popular questions from this chapter

For each of the following molecules or ions of sulfur and oxygen, write a single Lewis structure that obeys the octet rule, and calculate the oxidation numbers and formal charges on all the atoms: (a) SO \(_{2},(\mathbf{b}) \mathrm{SO}_{3},(\mathrm{c}) \mathrm{SO}_{3}^{2-}\) (d) Arrange these molecules/ions in order of increasing \(S-O\) bond length.

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(a) Construct a Lewis structure for hydrogen peroxide, \(\mathrm{H}_{2} \mathrm{O}_{2}\) in which each atom achieves an octet of electrons. (b) How many bonding electrons are between the two oxygen atoms? (c) Do you expect the \(\mathrm{O}-\mathrm{O}\) bond in \(\mathrm{H}_{2} \mathrm{O}_{2}\) to be longer or shorter than the \(\mathrm{O}-\mathrm{O}\) bond in \(\mathrm{O}_{2} ?\) Explain.

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Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, \(\mathrm{H}_{2} \mathrm{PO}_{4}^{-}\) , in which the \(\mathrm{H}\) atoms are bonded to \(\mathrm{O}\) atoms. (a) What is the predicted dominant Lewis structure if satisfying the octet rule is the top criterion? (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?

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