(a) What is a catalyst? (b) What is the difference between a homogeneous and a heterogeneous catalyst? (c) Do catalysts affect the overall enthalpy change for a reaction, the activation energy, or both?

Short Answer

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(a) A catalyst is a substance that speeds up a chemical reaction by lowering its activation energy, without being consumed or permanently altered in the process. It provides an alternative reaction pathway with a lower activation energy. (b) A homogeneous catalyst is in the same phase as the reactants, while a heterogeneous catalyst is in a different phase than the reactants. For example, a homogeneous catalyst could be a liquid dissolved in a liquid, while a heterogeneous catalyst could be a solid interacting with a gas or liquid. (c) Catalysts do not affect the overall enthalpy change (\(\Delta H\)) for a reaction but lower the activation energy (\(\Delta E_a\)) for the reaction. This makes it easier for the reactants to approach the transition state and form products, resulting in a faster overall reaction.

Step by step solution

01

(a) Define a catalyst

A catalyst is a substance that speeds up a chemical reaction by lowering its activation energy, without being consumed or permanently altered in the process. Catalysts work by providing an alternative reaction pathway with a lower activation energy.
02

(b) Explain the difference between a homogeneous and a heterogeneous catalyst

A homogeneous catalyst is a catalyst that is in the same phase as the reactants, while a heterogeneous catalyst is in a different phase than the reactants. For example, a homogeneous catalyst could be a liquid dissolved in a liquid, while a heterogeneous catalyst could be a solid interacting with a gas or liquid.
03

(c) Discuss the effect of catalysts on the overall enthalpy change and activation energy

Catalysts do not affect the overall enthalpy change (\(\Delta H\)) for a reaction, as they only provide an alternative reaction pathway. The overall change in energy for the reaction remains the same. However, catalysts do lower the activation energy (\(\Delta E_a\)) for a reaction, which is the minimum energy required for the reactants to undergo a chemical reaction. This makes it easier for the reactants to approach the transition state and subsequently form products, resulting in a faster overall reaction.

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Most popular questions from this chapter

Cobalt-60 is used in radiation therapy to treat cancer. It has a first-order rate constant for radioactive decay of $k=1.31 \times 10^{-1} \mathrm{yr}^{-1}$. Another radioactive isotope, iron59, which is used as a tracer in the study of iron metabolism, has a rate constant of $k=1.55 \times 10^{-2}\( day \)^{-1}$. (a) What are the half-lives of these two isotopes? (b) Which one decays at a faster rate? (c) How much of a 1.00-mg sample of each isotope remains after three half-lives? How much of a \(1.00-\mathrm{mg}\) sample of each isotope remains after five days?

(a) The activation energy for the reaction $\mathrm{A}(g) \longrightarrow \mathrm{B}(g)\( is \)100 \mathrm{~kJ} / \mathrm{mol}$. Calculate the fraction of the molecule A that has an energy equal to or greater than the activation energy at \(400 \mathrm{~K} .(\mathbf{b})\) Calculate this fraction for a temperature of \(500 \mathrm{~K}\). What is the ratio of the fraction at $500 \mathrm{~K}\( to that at \)400 \mathrm{~K}$ ?

The decomposition of hydrogen peroxide is catalyzed by iodide ion. The catalyzed reaction is thought to proceed by a two-step mechanism: $$ \begin{aligned} \mathrm{H}_{2} \mathrm{O}_{2}(a q)+\mathrm{I}^{-}(a q) & \longrightarrow \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{IO}^{-}(a q)(\text { slow }) \\ \mathrm{IO}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}_{2}(a q) & \longrightarrow \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{O}_{2}(g)+\mathrm{I}^{-}(a q) \quad(\text { fast }) \end{aligned} $$ (a) Write the chemical equation for the overall process. (b) Identify the intermediate, if any, in the mechanism. (c) Assuming that the first step of the mechanism is rate determining, predict the rate law for the overall process.

(a) Can an intermediate appear as a reactant in the first step of a reaction mechanism? (b) On a reaction energy profile diagram, is an intermediate represented as a peak or a valley? (c) If a molecule like \(\mathrm{Cl}_{2}\) falls apart in an elementary reaction, what is the molecularity of the reaction?

(a) The gas-phase decomposition of sulfuryl chloride $\left(\mathrm{SO}_{2} \mathrm{Cl}_{2}\right), \mathrm{SO}_{2} \mathrm{Cl}_{2}(g) \longrightarrow \mathrm{SO}_{2}(g)+\mathrm{Cl}_{2}(g)\( is first order in \)\mathrm{SO}_{2} \mathrm{Cl}_{2}\(. At \)300^{\circ} \mathrm{C}$ the half-life for this process is two and a half days. What is the rate constant at this temperature? (b) At \(400^{\circ} \mathrm{C}\) the rate constant is \(0.19 \mathrm{~min}^{-1}\). What is the half-life at this temperature?

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