Chapter 16: Problem 13
\(\mathrm{NH}_{3}(g)\) and \(\mathrm{HCl}(g)\) react to form the ionic solid \(\mathrm{NH}_{4} \mathrm{Cl}(s) .\) Which substance is the Brønsted-Lowry acid in this reaction? Which is the Brønsted-Lowry base?
Chapter 16: Problem 13
\(\mathrm{NH}_{3}(g)\) and \(\mathrm{HCl}(g)\) react to form the ionic solid \(\mathrm{NH}_{4} \mathrm{Cl}(s) .\) Which substance is the Brønsted-Lowry acid in this reaction? Which is the Brønsted-Lowry base?
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Get started for freeCalculate the molar concentration of \(\mathrm{OH}^{-}\) in a \(0.050 \mathrm{M}\) solution of ethylamine $\left(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{NH}_{2} ; K_{b}=6.4 \times 10^{-4}\right) .$ Calculate the \(\mathrm{pH}\) of this solution.
Based on their compositions and structures and on conjugate acid-base relationships, select the stronger base in each of the following pairs: (a) \(\mathrm{BrO}^{-}\) or \(\mathrm{ClO}^{-},(\mathbf{b}) \mathrm{BrO}^{-}\) or \(\mathrm{BrO}_{2}^{-}\), (c) \(\mathrm{HPO}_{4}^{2-}\) or $\mathrm{H}_{2} \mathrm{PO}_{4}^{-}$.
Identify the Lewis acid and Lewis base among the reactants in each of the following reactions: (a) $\mathrm{Fe}\left(\mathrm{ClO}_{4}\right)_{3}(s)+6 \mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons$ $$ \left[\mathrm{Fe}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]^{3+}(a q)+3 \mathrm{ClO}_{4}^{-}(a q) $$ (b) $\mathrm{CN}^{-}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{HCN}(a q)+\mathrm{OH}^{-}(a q)$ (c) $\left(\mathrm{CH}_{3}\right)_{3} \mathrm{~N}(g)+\mathrm{BF}_{3}(g) \rightleftharpoons\left(\mathrm{CH}_{3}\right)_{3} \mathrm{NBF}_{3}(s)$ (d) $\mathrm{HIO}(l q)+\mathrm{NH}_{2}^{-}(l q) \rightleftharpoons \mathrm{NH}_{3}(l q)+\mathrm{IO}^{-}(l q)$ (lg denotes liquid ammonia as solvent)
(a) Write an equation for the react ion in which \(\mathrm{HSO}_{4}^{-}(a q)\) acts as a base in \(\mathrm{H}_{2} \mathrm{O}(l) .(\mathbf{b})\) Write an equation for the reaction in which \(\mathrm{HSO}_{4}^{-}(a q)\) acts as an acid in \(\mathrm{H}_{2} \mathrm{O}(I) \cdot(\mathbf{c})\) What is the conjugate acid of \(\mathrm{HSO}_{4}^{-}(a q) ?\) What is its conjugate base?
Based on their compositions and structures and on conjugate acid-base relationships, select the stronger base in each of the following pairs: (a) \(\mathrm{NO}_{3}^{-}\) or \(\mathrm{NO}_{2}^{-},\) (b) \(\mathrm{PO}_{4}^{3-}\) or \(\mathrm{AsO}_{4}^{3-}\), (c) \(\mathrm{HCO}_{3}^{-}\) or \(\mathrm{CO}_{3}^{2-}\).
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