Chapter 18: Problem 2
Molecules in the upper atmosphere tend to contain double and triple bonds rather than single bonds. Suggest an explanation. [Section 18.1]
Chapter 18: Problem 2
Molecules in the upper atmosphere tend to contain double and triple bonds rather than single bonds. Suggest an explanation. [Section 18.1]
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Get started for freeBioremediation is the process by which bacteria repair their environment in response, for example, to an oil spill. The efficiency of bacteria for "eating" hydrocarbons depends on the amount of oxygen in the system, \(\mathrm{pH}\), temperature, and many other factors. In a certain oil spill, hydrocarbons from the oil disappeared with a first-order rate constant of $2 \times 10^{-6} \mathrm{~s}^{-1}$. At that rate, how many days would it take for the hydrocarbons to decrease to \(10 \%\) of their initial value?
Common lab spectrometers can detect absorbance down to 0.0002 with good reliability. Consider a dissolved harmful organic substance with a molar mass of \(120.5 \mathrm{~g} / \mathrm{mol}\), which can be detected in this spectrometer. It shows an extinction coefficient of $\varepsilon=1.43 \times 10^{3} \mathrm{M}^{-1} \mathrm{~cm}^{-1}$ at 320 \(\mathrm{nm}\), its absorption maximum (A Closer Look, p. 620). (a) Calculate the minimum concentration of the organic substance detectable by this spectrometer (path length \(1 \mathrm{~cm}\) ). (b) Convert the minimum observable molarity to ppb.
Explain, using Le Châtelier's principle, why the equilibrium constant for the formation of \(\mathrm{NO}\) from \(\mathrm{N}_{2}\) and \(\mathrm{O}_{2}\) increases with increasing temperature, whereas the equilibrium constant for the formation of \(\mathrm{NO}_{2}\) from \(\mathrm{NO}\) and \(\mathrm{O}_{2}\) decreases with increasing temperature.
One of the principles of green chemistry is that it is better to use as few steps as possible in making new chemicals. In what ways does following this rule advance the goals of green chemistry? How does this principle relate to energy efficiency?
It was estimated that the eruption of the Mount Pinatubo volcano resulted in the injection of 20 million metric tons of \(\mathrm{SO}_{2}\) into the atmosphere. Most of this \(\mathrm{SO}_{2}\) underwent oxidation to \(\mathrm{SO}_{3},\) which reacts with atmospheric water to form an aerosol. (a) Write chemical equations for the processes leading to formation of the aerosol. (b) The aerosols caused a \(0.5-0.6^{\circ} \mathrm{C}\) drop in surface temperature in the northern hemisphere. What is the mechanism by which this occurs? (c) The sulfate aerosols, as they are called, also cause loss of ozone from the stratosphere. How might this occur?
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