Chapter 18: Problem 47
List the common products formed when an organic material containing the elements carbon, hydrogen, oxygen, sulfur, and nitrogen decomposes (a) under aerobic conditions, (b) under anaerobic conditions.
Chapter 18: Problem 47
List the common products formed when an organic material containing the elements carbon, hydrogen, oxygen, sulfur, and nitrogen decomposes (a) under aerobic conditions, (b) under anaerobic conditions.
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Get started for freeA 500 megawatt electrical power plant typically burned 1,430,000 metric tons of coal in a year. (a) Assuming that the coal was \(80 \%\) carbon and \(3 \%\) sulfur and that combustion was complete, calculate the number of tons of carbon dioxide and sulfur dioxide produced by the plant during the year. (b) If \(50 \%\) of the \(\mathrm{SO}_{2}\) could be removed by reaction with powdered \(\mathrm{CaO}\) to form \(\mathrm{CaSO}_{3}\), how many tons of \(\mathrm{CaSO}_{3}\) would be produced?
Sodium stearate $\left(\mathrm{C}_{18} \mathrm{H}_{35} \mathrm{O}_{2} \mathrm{Na}\right)$ is the most common soap. Assume that the stearate anion undergoes aerobic decomposition in the following manner: $$ \begin{aligned} \mathrm{C}_{18} \mathrm{H}_{35} \mathrm{O}_{2}^{-}(a q)+26 \mathrm{O}_{2}(a q) & \longrightarrow \\ & 17 \mathrm{CO}_{2}(a q)+17 \mathrm{H}_{2} \mathrm{O}(l)+\mathrm{HCO}_{3}^{-}(a q) \end{aligned} $$ What is the total mass of \(\mathrm{O}_{2}\) required to biodegrade $3.0 \mathrm{~g}$ of this substance?
Alcohol-based fuels for automobiles lead to the production of formaldehyde \(\left(\mathrm{CH}_{2} \mathrm{O}\right)\) in exhaust gases. Formaldehyde undergoes photodissociation, which contributes to photochemical smog: $$ \mathrm{CH}_{2} \mathrm{O}+h \nu \longrightarrow \mathrm{CHO}+\mathrm{H} $$ The maximum wavelength of light that can cause this reaction is $335 \mathrm{nm} .(\mathbf{a})$ In what part of the electromagnetic spectrum is light with this wavelength found? (b) What is the maximum strength of a bond, in \(\mathrm{kJ} / \mathrm{mol}\), that can be broken by absorption of a photon of 335 -nm light? (c) Compare your answer from part (b) to the appropriate value from Table 8.3 . What do you conclude about \(\mathrm{C}-\mathrm{H}\) bond energy in formaldehyde? (d) Write out the formaldehyde photodissociation reaction, showing Lewis-dot structures.
The ultraviolet spectrum can be divided into three regions based on wavelength: UV-A (315-400 nm), UV-B (280-315 \(\mathrm{nm})\), and UV-C \((100-280 \mathrm{nm})\). (a) Photons from which region have the highest energy and therefore are the most harmful to living tissue? (b) In the absence of ozone, which of these three regions, if any, are absorbed by the atmosphere? (c) When appropriate concentrations of ozone are present in the stratosphere, is all of the UV light absorbed before reaching the Earth's surface? If not, which region or regions are not filtered out?
The average bond enthalpies of the \(\mathrm{C}-\mathrm{C}\) and \(\mathrm{C}-\mathrm{H}\) bonds are \(348 \mathrm{~kJ} / \mathrm{mol}\) and $413 \mathrm{~kJ} / \mathrm{mol}$, respectively. (a) What is the maximum wavelength that a photon can possess and still have sufficient energy to break the \(\mathrm{C}-\mathrm{H}\) and \(\mathrm{C}-\mathrm{C}\) bonds, respectively? (b) Given the fact that \(\mathrm{O}_{2}, \mathrm{~N}_{2},\) and \(\mathrm{O}\) in the upper atmosphere absorb most of the light with wavelengths shorter than $240 \mathrm{nm}$, would you expect the photodissociation of \(\mathrm{C}-\mathrm{C}\) and \(\mathrm{C}-\mathrm{H}\) bonds to be significant in the lower atmosphere?
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