Chapter 18: Problem 56
Discuss how catalysts can make processes more energy efficient.
Chapter 18: Problem 56
Discuss how catalysts can make processes more energy efficient.
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Get started for freeThe degradation of \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) (an HFC) by OH radicals in the troposphere is first order in each reactant and has a rate constant of \(k=2.1 \times 10^{8} \mathrm{M}^{-1} \mathrm{~s}^{-1}\) at \(10^{\circ} \mathrm{C}\). If the tropospheric concentrations of \(\mathrm{OH}\) and \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) are \(1.0 \times 10^{12}\) and \(7.5 \times 10^{14}\) molecules \(/ \mathrm{m}^{3}\), respectively, what is the rate of reaction at this temperature in \(M /\) s?
The atmosphere of Mars is \(96 \% \mathrm{CO}_{2}\), with a pressure of approximately \(0.6 \mathrm{kPa}\) at the surface. Based on measurements taken over a period of several years by the Rover Environmental Monitoring Station (REMS), the average daytime temperature at the REMS location on Mars is \(-5.7^{\circ} \mathrm{C},\) while the average nighttime temperature is \(-79^{\circ} \mathrm{C}\). This daily variation in temperature is much larger than what we experience on Earth. What factor plays the largest role in this wide temperature variation, the composition or the density of the atmosphere?
Hydrogen phosphate \(\left(\mathrm{HPO}_{4}^{2-}\right)\) can be removed in water treatment by the addition of slaked lime, $\mathrm{Ca}(\mathrm{OH})_{2} .$ Write a balanced chemical equation for the reaction (using ions as reactant), in which \(\mathrm{Ca}_{5}(\mathrm{OH})\left(\mathrm{PO}_{4}\right)_{3}\) forms as a precipitate.
The enthalpy of evaporation of water is \(40.67 \mathrm{~kJ} / \mathrm{mol}\). Sunlight striking Earth's surface supplies \(168 \mathrm{~W}\) per square meter \((1 \mathrm{~W}=1 \mathrm{watt}=1 \mathrm{~J} / \mathrm{s}) .(\mathbf{a})\) Assuming that evaporation of water is due only to energy input from the Sun, calculate how many grams of water could be evaporated from a 1.00 square meter patch of ocean over a 12 -h day. (b) The specific heat capacity of liquid water is \(4.184 \mathrm{~J} / \mathrm{g}^{\circ} \mathrm{C}\). If the initial surface temperature of a 1.00 square meter patch of ocean is $26^{\circ} \mathrm{C}\(, what is its final temperature after being in sunlight for \)12 \mathrm{~h}$, assuming no phase changes and assuming that sunlight penetrates uniformly to depth of \(10.0 \mathrm{~cm} ?\)
The dissociation energy of a carbon-iodine bond is typically about $240 \mathrm{~kJ} / \mathrm{mol} .(\mathbf{a})$ What is the maximum wavelength of photons that can cause \(\mathrm{C}-\mathrm{I}\) bond dissociation? (b) Which kind of electromagnetic radiation-ultraviolet, visible, or infrared- does the wavelength you calculated in part (a) correspond to?
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