Chapter 18: Problem 65
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
Chapter 18: Problem 65
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
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Get started for freeThe valuable polymer polyurethane is made by a condensation reaction of alcohols (ROH) with compounds that contain an isocyanate group (RNCO). Two reactions that can generate a urethane monomer are shown here: (a) Which process, i or ii, is greener? Explain. (b) What are the hybridization and geometry of the carbon atoms in each C-containing compound in each reaction? (c) If you wanted to promote the formation of the isocyanate intermediate in each reaction, what could you do, using Le Châtelier's principle?
List the common products formed when an organic material containing the elements carbon, hydrogen, oxygen, sulfur, and nitrogen decomposes (a) under aerobic conditions, (b) under anaerobic conditions.
Write balanced chemical equations for each of the following reactions: (a) The carbon dioxide molecule undergoes photodissociation in the upper atmosphere. (b) The carbon dioxide molecule undergoes photoionization in the upper atmosphere. (c) Carbon monoxide undergoes oxidation by ozone in the stratosphere. (d) Carbon dioxide dissolves in water to form hydrogen carbonate.
Explain, using Le Châtelier's principle, why the equilibrium constant for the formation of \(\mathrm{NO}\) from \(\mathrm{N}_{2}\) and \(\mathrm{O}_{2}\) increases with increasing temperature, whereas the equilibrium constant for the formation of \(\mathrm{NO}_{2}\) from \(\mathrm{NO}\) and \(\mathrm{O}_{2}\) decreases with increasing temperature.
In \(\mathrm{CH}_{3} \mathrm{I}\) the \(\mathrm{C}\) - I bond-dissociation energy is \(241 \mathrm{~kJ} / \mathrm{mol}\). In \(\mathrm{C}_{6} \mathrm{H}_{5}\) I the \(\mathrm{C}-\) I bond-dissociation energy is \(280 \mathrm{~kJ} / \mathrm{mol}\). What is the range of wavelengths of photons that can cause \(\mathrm{C}-\mathrm{I}\) bond rupture in one molecule but not in the other?
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