Chapter 20: Problem 2
You may have heard that "antioxidants" are good for your health. Is an "antioxidant" an oxidizing agent or a reducing agent?
Chapter 20: Problem 2
You may have heard that "antioxidants" are good for your health. Is an "antioxidant" an oxidizing agent or a reducing agent?
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Get started for freeIron corrodes to produce rust, \(\mathrm{Fe}_{2} \mathrm{O}_{3},\) but other corrosion products that can form are \(\mathrm{Fe}(\mathrm{O})(\mathrm{OH})\), iron oxyhydroxide, and magnetite, \(\mathrm{Fe}_{3} \mathrm{O}_{4} .\) (a) What is the oxidation number of Fe in iron oxyhydroxide, assuming oxygen's oxidation number is \(-2 ?(\mathbf{b})\) The oxidation number for Fe in magnetite was controversial for a long time. If we assume that oxygen's oxidation number is \(-2,\) and Fe has a unique oxidation number, what is the oxidation number for Fe in magnetite? (c) It turns out that there are two different kinds of Fe in magnetite that have different oxidation numbers. Suggest what these oxidation numbers are and what their relative stoichiometry must be, assuming oxygen's oxidation number is -2 .
(a) In the Nernst equation, what is the numerical value of the reaction quotient, \(Q,\) under standard conditions? (b) Can the Nernst equation be used at temperatures other than room temperature?
Complete and balance the following half-reactions. In each case indicate whether the half-reaction is an oxidation or a reduction. (a) \(\mathrm{Mo}^{3+}(a q) \longrightarrow \mathrm{Mo}(s)\) (acidic solution) (b) $\mathrm{H}_{2} \mathrm{SO}_{3}(a q) \longrightarrow \mathrm{SO}_{4}^{2-}(a q)$ (acidic solution) (c) \(\mathrm{NO}_{3}^{-}(a q) \longrightarrow \mathrm{NO}(g)\) (acidic solution) (d) \(\mathrm{O}_{2}(g) \longrightarrow \mathrm{H}_{2} \mathrm{O}(l)\) (acidic solution) (e) \(\mathrm{O}_{2}(g) \longrightarrow \mathrm{H}_{2} \mathrm{O}(l)\) (basic solution) (f) \(\mathrm{Mn}^{2+}(a q) \longrightarrow \mathrm{MnO}_{2}(s)\) (basic solution) (g) $\mathrm{Cr}(\mathrm{OH})_{3}(s) \longrightarrow \mathrm{CrO}_{4}^{2-}(a q)$ (basic solution)
(a) Write the half-reaction that occurs at an oxygen electrode in acidic aqueous solution when it serves as the cathode of a voltaic cell. (b) Write the half-reaction that occurs at an oxygen electrode in acidic aqueous solution when it serves as the anode of a voltaic cell. (c) What is standard about the standard oxygen electrode?
Consider the half-reaction $\mathrm{Ag}^{+}(a q)+\mathrm{e}^{-} \longrightarrow \mathrm{Ag}(s)$ (a) Which of the lines in the following diagram indicates how the reduction potential varies with the concentration of \(\mathrm{Ag}^{+}(a q) ?(\mathbf{b})\) What is the value of \(E_{\text {red }}\) when \(\log \left[\mathrm{Ag}^{+}\right]=0 ?\)
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