Name the following compounds and assign oxidation states to the halogens in them: (a) \(\mathrm{Co}\left(1 \mathrm{O}_{3}\right)_{3},\) (b) \(\mathrm{Ca}\left(1 \mathrm{O}_{4}\right)_{2}\), (c) \(\mathrm{PF}_{6}^{-},(\mathbf{d}) \mathrm{ICl}_{4}^{-}\), (e) \(\mathrm{HBrO},\) (f) AtH.

Short Answer

Expert verified
The names of the given compounds are (a) Cobalt(III) Iodate, (b) Calcium Periodate, (c) Hexafluorophosphate ion, (d) Tetrachloroiodate ion, (e) Hypobromous acid, and (f) Astatine Hydride. The oxidation states of the halogens in each compound are: (a) Iodine: +5, (b) Iodine: +7, (c) Fluorine: -1, (d) Iodine: +3 and Chlorine: -1, (e) Bromine: +1, and (f) Astatine: -1.

Step by step solution

01

Naming each compound

(a) \(\mathrm{Co}\left(1 \mathrm{O}_{3}\right)_{3}\): This compound contains Cobalt (Co) and the polyatomic ion IO₃⁻ which is Iodate. So, the name of the compound is Cobalt(III) Iodate. (b) \(\mathrm{Ca}\left(1 \mathrm{O}_{4}\right)_{2}\): This compound contains Calcium (Ca) and the polyatomic ion IO₄⁻ which is Periodate. So, the name of the compound is Calcium Periodate. (c) \(\mathrm{PF}_{6}^{-}\): This compound contains Phosphorus (P) and Fluorine (F) with a -1 charge. The name of this compound is Hexafluorophosphate ion. (d) \(\mathrm{ICl}_{4}^{-}\): This compound contains Iodine (I) and Chlorine (Cl) with a -1 charge. The name of this compound is Tetrachloroiodate ion. (e) \(\mathrm{HBrO}\): This compound contains Hydrogen (H), Bromine (Br), and Oxygen (O). The name of this compound is Hypobromous acid. (f) AtH: This compound contains Hydrogen (H) and Astatine (At). The name of this compound is Astatine Hydride.
02

Determine the oxidation states for halogens

(a) \(\mathrm{Co}\left(1 \mathrm{O}_{3}\right)_{3}\): Here, the halogen is Iodine (I). To determine its oxidation state, we use some of the rules for oxidation states: 1. The sum of the oxidation states in a neutral compound is 0. 2. The oxidation state of oxygen in most compounds is -2. IO₃⁻ oxidation states: I + 3(-2) = -1 I = +5, so the oxidation state of Iodine in this compound is +5. (b) \(\mathrm{Ca}\left(1 \mathrm{O}_{4}\right)_{2}\): In this compound, the halogen is again Iodine (I). IO₄⁻ oxidation states: I + 4(-2) = -1 I = +7, so the oxidation state of Iodine in this compound is +7. (c) \(\mathrm{PF}_{6}^{-}\): In this compound, the halogen is Fluorine (F). PF₆⁻ oxidation states: P + 6(F) = -1 Since the oxidation state of F in compounds is always -1: P + 6(-1) = -1 P = +5, thus the oxidation state of Fluorine in this compound is -1. (d) \(\mathrm{ICl}_{4}^{-}\): Here, the halogens are Iodine (I) and Chlorine (Cl). ICl₄⁻ oxidation states: I + 4(Cl) = -1 Since the oxidation state of Cl in compounds is usually -1: I + 4(-1) = -1 I = +3, so the oxidation state of Iodine in this compound is +3, and the oxidation state of Chlorine is -1. (e) \(\mathrm{HBrO}\): In this compound, the halogen is Bromine (Br). HBrO oxidation states: H + Br + O = 0 Using standard oxidation states for H (+1) and O (-2), +1 + Br - 2 = 0 Br = +1, thus the oxidation state of Bromine in this compound is +1. (f) AtH: In this compound, the halogen is Astatine (At). AtH oxidation states: At + H = 0 Using standard oxidation states for H (+1), At + 1 = 0 At = -1, so the oxidation state of Astatine in this compound is -1.

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