Chapter 23: Problem 14
Among the period 4 transition metals \((\mathrm{Sc}-\mathrm{Zn}),\) which elements do not form ions where there are partially filled \(3 d\) orbitals?
Chapter 23: Problem 14
Among the period 4 transition metals \((\mathrm{Sc}-\mathrm{Zn}),\) which elements do not form ions where there are partially filled \(3 d\) orbitals?
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Get started for freeDraw the crystal-field energy-level diagrams and show the placement of electrons for the following complexes: (a) \(\left[\mathrm{VCl}_{6}\right]^{3-},(\mathbf{b})\left[\mathrm{FeF}_{6}\right]^{3-}\) (a high-spin complex), (c) \(\left[\mathrm{Ru}(\text { bipy })_{3}\right]^{3+}\) (a low-spin complex), (d) \(\left[\mathrm{NiCl}_{4}\right]^{2-}\) (tetrahedral), (e) \(\left[\mathrm{PtBr}_{6}\right]^{2-},(\mathbf{f})\left[\mathrm{Ti}(\mathrm{en})_{3}\right]^{2+}\).
The complexes \(\left[\mathrm{CrBr}_{6}\right]^{3-}\) and \(\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{6}\right]^{3+}\) are both known. (a) Draw the \(d\) -orbital energy-level diagram for octahedral \(\mathrm{Cr}(\mathrm{III})\) complexes. (b) What gives rise to the colors of these complexes? (c) Which of the two complexes would you expect to absorb light of higher energy?
Draw the structure for $\mathrm{Pt}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)\left(\mathrm{NH}_{3}\right)_{2}$ and use it to answer the following questions: (a) What is the coordination number for platinum in this complex? (b) What is the coordination geometry? (c) What is the oxidation state of the platinum? (d) How many unpaired electrons are there? [Sections 23.2 and 23.6\(]\)
When Alfred Werner was developing the field of coordination chemistry, it was argued by some that the optical activity he observed in the chiral complexes he had prepared was due to the presence of carbon atoms in the molecule. To disprove this argument, Werner synthesized a chiral complex of cobalt that had no carbon atoms in it, and he was able to resolve it into its enantiomers. Design a cobalt(III) complex that would be chiral if it could be synthesized and that contains no carbon atoms. (It may not be possible to synthesize the complex you design, but we will not worry about that for now.)
Four-coordinate metals can have either a tetrahedral or a square-planar geometry; both possibilities are shown here for $\left[\mathrm{Pt} \mathrm{Cl}_{2}\left(\mathrm{NH}_{3}\right)_{2}\right] .(\mathbf{a})$ What is the name of this molecule? (b) Would the tetrahedral molecule have a geometric isomer? (c) Would the tetrahedral molecule be diamagnetic or paramagnetic? (d) Would the square- planar molecule have a geometric isomer? (e) Would the square-planar molecule be diamagnetic or paramagnetic? (f) Would determining the number of geometric isomers help you distinguish between the tetrahedral and square-planar geometries? (g) Would measuring the molecule's response to a magnetic field help you distinguish between the two geometries? [Sections \(23.4-23.6]\)
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