Chapter 23: Problem 15
Write out the ground-state electron configurations of (a) \(\mathrm{Sc}^{2+}\) (b) \(\mathrm{Mo}^{2+}\) (c) \(\mathrm{Rh}^{3+}\), (d) \(\mathrm{Fe}^{3+}\).
Chapter 23: Problem 15
Write out the ground-state electron configurations of (a) \(\mathrm{Sc}^{2+}\) (b) \(\mathrm{Mo}^{2+}\) (c) \(\mathrm{Rh}^{3+}\), (d) \(\mathrm{Fe}^{3+}\).
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Get started for freeIndicate the likely coordination number of the metal in each of the following complexes: (a) $\left[\mathrm{Ru}(\text { bipy })_{3}\right]\left(\mathrm{NO}_{3}\right)_{2}$ (b) $\operatorname{Re}(\text { o-phen })_{2}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{2}$ (c) \(\mathrm{Pd}(\mathrm{PPh} 3)_{3} \mathrm{Cl}\) (d) \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{Mn}(\mathrm{EDTA})\)
Determine if each of the following complexes exhibits geometric isomerism. If geometric isomers exist, determine how many there are. (a) tetrahedral $\left[\mathrm{Cd}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2} \mathrm{Cl}_{2}\right],(\mathbf{b})$ square-pla- \(\operatorname{nar}\left[\operatorname{IrCl}_{2}\left(\mathrm{PH}_{3}\right)_{2}\right]^{-},(\mathbf{c})\) octahedral $\left[\mathrm{Fe}(o \text { -phen })_{2} \mathrm{Cl}_{2}\right]^{+} .$
For each of the following metals, write the electronic configuration of the atom and its \(3+\) ion: (a) Fe, (b) Mo, (c) Co. Draw the crystal-field energy-level diagram for the \(d\) orbitals of an octahedral complex, and show the placement of the \(d\) electrons for each \(3+\) ion, assuming a weak-field complex. How many unpaired electrons are there in each case?
The ion \(\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]^{3-}\) has one unpaired electron, whereas \(\left[\mathrm{Fe}(\mathrm{NCS})_{6}\right]^{3-}\) has five unpaired electrons. From these results, what can you conclude about whether each complex is high spin or low spin? What can you say about the placement of \(\mathrm{NCS}^{-}\) in the spectrochemical series?
Give the number of (valence) \(d\) electrons associated with the central metal ion in each of the following complexes: (a) $\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2}\right] \mathrm{Cl}_{2},$, (b) $\mathrm{K}_{2}\left[\mathrm{Cu}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{2}\right]$, (c) \(\left[\mathrm{Os}(\mathrm{en})_{3}\right] \mathrm{Cl}_{3}\), (d) $[\mathrm{Cr}(\mathrm{EDTA})] \mathrm{SO}_{4},(\mathbf{e})\left[\mathrm{Cd}\left(\mathrm{H}_{2} ,\mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}$.
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