Chapter 23: Problem 17
Which type of substance is attracted by a magnetic field, a diamagnetic substance or a paramagnetic substance?
Chapter 23: Problem 17
Which type of substance is attracted by a magnetic field, a diamagnetic substance or a paramagnetic substance?
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Get started for freeWrite the formula for each of the following compounds, being sure to use brackets to indicate the coordination sphere: (a) hexaammineiron(II) nitrate (b) tetraaquadibromochromium(III) perchlorate (c) ammonium hexachloropalladate(IV) (d) diammineoxolatonickel(II) (e) Hexaamminemolybdenum(III) tetrachlorocuprate(II)
Among the period 4 transition metals \((\mathrm{Sc}-\mathrm{Zn}),\) which elements do not form ions where there are partially filled \(3 d\) orbitals?
For each of the following molecules or polyatomic ions, draw the Lewis structure and indicate if it can act as a monodentate ligand, a bidentate ligand, or is unlikely to act as a ligand at all: (a) ethylamine, \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{NH}_{2}\), (b) trimethylphosphine, \(\mathrm{P}\left(\mathrm{CH}_{3}\right)_{3}\), (c) carbonate, \(\mathrm{CO}_{3}^{2-}\) (d) ethane, \(\mathrm{C}_{2} \mathrm{H}_{6}\).
Determine if each of the following complexes exhibits geometric isomerism. If geometric isomers exist, determine how many there are. (a) tetrahedral $\left[\mathrm{Cd}\left(\mathrm{H}_{2} \mathrm{O}\right)_{2} \mathrm{Cl}_{2}\right],(\mathbf{b})$ square-pla- \(\operatorname{nar}\left[\operatorname{IrCl}_{2}\left(\mathrm{PH}_{3}\right)_{2}\right]^{-},(\mathbf{c})\) octahedral $\left[\mathrm{Fe}(o \text { -phen })_{2} \mathrm{Cl}_{2}\right]^{+} .$
Carbon monoxide, CO, is an important ligand in coordination chemistry. When CO is reacted with nickel metal, the product is \(\left[\mathrm{Ni}(\mathrm{CO})_{4}\right],\) which is a toxic, pale yellow liquid. (a) What is the oxidation number for nickel in this compound? (b) Given that \(\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]\) is a diamagnetic molecule with a tetrahedral geometry, what is the electron configuration of nickel in this compound? (c) Write the name for \(\left[\mathrm{Ni}(\mathrm{CO})_{4}\right]\) using the nomenclature rules for coordination compounds.
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