Write names for the following coordination compounds: (a) \(\mathrm{Na}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{5} \mathrm{NO}\right]\) (b) \(\left[\mathrm{CoO}\left(\mathrm{NH}_{3}\right)_{5}\right] \mathrm{Br}\) (c) \(\mathrm{Na}_{2}\left[\mathrm{NiBr}_{4}\right]\) (d) $\left[\mathrm{Rh}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]_{3}$

Short Answer

Expert verified
The names for the coordination compounds are: (a) Pentaamminecyanidonitrosyliron(III) (b) Pentaammineoxocobalt(III) bromide (c) Tetrabromidonickel(II) sodium (d) Hexaaquarhodium(III) tris(dicyanoargentate(I))

Step by step solution

01

(a) Naming Na3[Fe(CN)5NO]

First, identify the metal and its oxidation state. In this compound, the metal is iron (Fe). The ligands include five cyanides (CN-) and one nitrosyl (NO). The total charge of the coordination complex is -3, as there are three sodium ions (Na+) in the compound. Iron's oxidation state is +3, which balances the charge. The name for the coordination compound is then: Pentaamminecyanidonitrosyliron(III)
02

(b) Naming [CoO(NH3)5]Br

Identify the metal and its oxidation state. In this compound, the metal is cobalt (Co). The ligands include one oxide (O2-) and five ammonia (NH3) molecules. The total charge of the coordination complex is +1, as there is one bromide ion (Br-) in the compound. Cobalt's oxidation state is +3, which balances the charge. The name for the coordination compound is: Pentaammineoxocobalt(III) bromide
03

(c) Naming Na2[NiBr4]

Identify the metal and its oxidation state. In this compound, the metal is nickel (Ni). The ligands include four bromides (Br-). The total charge of the coordination complex is -2, as there are two sodium ions (Na+) in the compound. Nickel's oxidation state is +2, which balances the charge. The name for the coordination compound is: Tetrabromidonickel(II) sodium
04

(d) Naming [Rh(H2O)6][Ag(CN)2]3

In this compound, there are two coordination complexes: [Rh(H2O)6] and [Ag(CN)2]. Identify the metal and its oxidation state in [Rh(H2O)6]. The metal is rhodium (Rh), and the ligands include six water (H2O) molecules. The charge of this complex is +3, which gives Rh an oxidation state of +3. The name for this coordination complex is: Hexaaquarhodium(III) Identify the metal and its oxidation state in [Ag(CN)2]. The metal is silver (Ag), and the ligands include two cyanides (CN-). The charge of this complex is -1, which gives Ag an oxidation state of +1. The name for this coordination complex is: Dicyanoargentate(I) Putting both names together, the name for the full coordination compound is: Hexaaquarhodium(III) tris(dicyanoargentate(I))

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Most popular questions from this chapter

Oxyhemoglobin, with an \(\mathrm{O}_{2}\) bound to iron, is a low-spin Fe(II) complex; deoxyhemoglobin, without the \(\mathrm{O}_{2}\) molecule, is a high- spin complex. (a) Assuming that the coordination environment about the metal is octahedral, how many unpaired electrons are centered on the metal ion in each case? (b) What ligand is coordinated to the iron in place of \(\mathrm{O}_{2}\) in deoxyhemoglobin? (c) Explain in a general way why the two forms of hemoglobin have different colors (hemoglobin is red, whereas deoxyhemoglobin has a bluish cast). (d) A 15-minute exposure to air containing 400 ppm of CO causes about \(10 \%\) of the hemoglobin in the blood to be converted into the carbon monoxide complex, called carboxyhemoglobin. What does this suggest about the relative equilibrium constants for binding of carbon monoxide and \(\mathrm{O}_{2}\) to hemoglobin? (e) CO is a strong-field ligand. What color might you expect carboxyhemoglobin to be?

The value of \(\Delta\) for the \(\left[\mathrm{MoI}_{6}\right]^{3-}\) complex is \(198.58 \mathrm{~kJ} / \mathrm{mol}\). Calculate the expected wavelength of the absorption corresponding to promotion of an electron from the lower energy to the higher-energy \(d\) -orbital set in this complex. Should the complex absorb in the visible range?

Give the number of (valence) \(d\) electrons associated with the central metal ion in each of the following complexes: (a) $\left[\mathrm{Pt}\left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2}\right] \mathrm{Cl}_{2}$, (b) $\mathrm{K}_{2}\left[\mathrm{Cu}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{2}\right]$, (c) \(\left[\mathrm{Os}(\mathrm{en})_{3}\right] \mathrm{Cl}_{3}\), (d) \([\mathrm{Cr}(\mathrm{EDTA})] \mathrm{SO}_{4}\), , (e) $\left[\mathrm{Cd}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right] \mathrm{Cl}_{2}$

Which periodic trend is partially responsible for the observation that the maximum oxidation state of the transition-metal elements peaks near groups 7 and \(8 ?(\mathbf{a})\) The number of valence electrons reaches a maximum at group 8. (b) The effective nuclear charge increases on moving left across each period. (c) The radii of the transition-metal elements reach a minimum for group \(8,\) and as the size of the atoms decreases it becomes easier to remove electrons.

Consider the following three complexes: \(\left(\right.\) Complex 1) $\left[\mathrm{Co}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Br}_{2}\right] \mathrm{Cl}$ 2) \(\left[\mathrm{Pd}\left(\mathrm{NH}_{3}\right)_{2}(\mathrm{ONO})_{2}\right]\) (Complex (Complex 3) $\left[\mathrm{V}(\mathrm{en})_{2} \mathrm{Cl}_{2}\right]^{+},$ Which of the three complexes can have (a) geometric isomers, (b) linkage isomers, (c) optical isomers, (d) coordinationsphere isomers?

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