Sketch the structure of the complex in each of the following compounds and give the full compound name: (a) $c i s-\left[\operatorname{PtBr} \mathrm{Cl}\left(\mathrm{NO}_{2}\right)_{2}\right]^{2-}$ (b) $\left[\mathrm{Mn}(\mathrm{CO})_{3}\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\right]^{+}$ (c) $\left.c i s-\left[\mathrm{Cr} \mathrm{Cl}_{4}\right)\left(\mathrm{OH}_{2}\right)_{2}\right]^{-}$ (d) trans-[Co(OH)(en) \(\left._{2} \mathrm{Cl}\right]^{+}\)

Short Answer

Expert verified
(a) The structure of cis-\([PtBrCl(NO2)_2]^{2-}\) is square planar, with Br and Cl cis to each other, and the two NO2 groups cis to each other as well. The full name is cis-dichlorodibromidoplatinum(II). (b) The structure of \([Mn(CO)_3(C_6H_6)]^{+}\) is tetrahedral, with three carbonyl ligands and one benzene ligand surrounding the manganese center. The full name is manganese(I) tricarbonylbenzene. (c) The structure of cis-\([CrCl_4(OH_2)_2]^{-}\) is octahedral, with two aqua ligands cis to each other and two of the four chlorine ligands cis to each other as well. The full name is cis-tetrachlorodihydroxochromium(III). (d) The structure of trans-\([Co(OH)(en)_2Cl]^{+}\) is octahedral, with hydroxide and chlorine ligands trans to each other. The full name is trans-chloridohydroxobis(ethylenediamine)cobalt(III).

Step by step solution

01

Identify the central atom

The central atom in this complex is Pt (platinum).
02

Identify the ligands

The ligands in the complex are Br (bromine), Cl (chlorine), and NO2 (nitrite).
03

Determine the geometry of the complex

The complex has four ligands bonded to the center. Thus, it most likely has a square planar geometry.
04

Sketch the structure and name the complex

In a cis configuration, similar ligands are positioned next to each other. In this case, Br and Cl are cis to each other, as are the two NO2 groups. The full name of this complex is cis-dichlorodibromidoplatinum(II). (b) Sketching structure and naming \([Mn(CO)_3(C_6H_6)]^{+}\)
05

Identify the central atom

The central atom in this complex is Mn (manganese).
06

Identify the ligands

The ligands in the complex are CO (carbonyl) and C6H6 (benzene).
07

Determine the geometry of the complex

The complex has four ligands bonded to the center. Thus, it most likely has a tetrahedral geometry.
08

Sketch the structure and name the complex

The structure can be sketched to show three carbonyl ligands and one benzene ligand around the manganese center. The full name of this complex is manganese(I) tricarbonylbenzene. (c) Sketching structure and naming cis-\([CrCl_4(OH_2)_2]^{-}\)
09

Identify the central atom

The central atom in this complex is Cr (chromium).
10

Identify the ligands

The ligands in the complex are Cl (chlorine) and OH2 (aqua).
11

Determine the geometry of the complex

The complex has six ligands bonded to the center. Thus, it most likely has an octahedral geometry.
12

Sketch the structure and name the complex

In a cis configuration, similar ligands are positioned next to each other. In this case, two aqua ligands are cis to each other, as are two of the four chlorine ligands. The full name of this complex is cis-tetrachlorodihydroxochromium(III). (d) Sketching structure and naming trans-\([Co(OH)(en)_2Cl]^{+}\)
13

Identify the central atom

The central atom in this complex is Co (cobalt).
14

Identify the ligands

The ligands in the complex are OH (hydroxide), en (ethylenediamine), and Cl (chlorine).
15

Determine the geometry of the complex

The complex has six ligands bonded to the center. Thus, it most likely has an octahedral geometry.
16

Sketch the structure and name the complex

In a trans configuration, opposite ligands are different. In this case, hydroxide and chlorine ligands are trans to each other. The full name of this complex is trans-chloridohydroxobis(ethylenediamine)cobalt(III).

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Most popular questions from this chapter

The complex \(\left[\mathrm{Mn}\left(\mathrm{NH}_{3}\right)_{6}\right]^{2+}\) contains five unpaired electrons. Sketch the energy-level diagram for the \(d\) orbitals, and indicate the placement of electrons for this complex ion. Is the ion a high-spin or a low-spin complex?

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