Chapter 3: Problem 33
What is the mass, in kilograms, of an Avogadro's number of people, if the average mass of a person is \(160 \mathrm{lb}\) ? How does this compare with the mass of Earth, \(5.98 \times 10^{24} \mathrm{~kg}\) ?
Chapter 3: Problem 33
What is the mass, in kilograms, of an Avogadro's number of people, if the average mass of a person is \(160 \mathrm{lb}\) ? How does this compare with the mass of Earth, \(5.98 \times 10^{24} \mathrm{~kg}\) ?
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Get started for freeWhat is the molecular formula of each of the following compounds? (a) empirical formula \(\mathrm{CH}_{3} \mathrm{O}\), molar mass $=62.0 \mathrm{~g} / \mathrm{mol}$ (b) empirical formula \(\mathrm{NH}_{2}\), molar mass $=32.0 \mathrm{~g} / \mathrm{mol}$
Hydrogen cyanide, HCN, is a poisonous gas. The lethal dose is approximately \(300 \mathrm{mg}\) HCN per kilogram of air when inhaled. (a) Calculate the amount of HCN that gives the lethal dose in a small laboratory room measuring \(3.5 \times 4.5 \times 2.5 \mathrm{~m}\). The density of air at \(26^{\circ} \mathrm{C}\) is $0.00118 \mathrm{~g} / \mathrm{cm}^{3} .(\mathbf{b})\( If the HCN is formed by reaction of \)\mathrm{NaCN}$ with an acid such as \(\mathrm{H}_{2} \mathrm{SO}_{4},\) what mass of NaCN gives the lethal dose in the room? $$ 2 \mathrm{NaCN}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{Na}_{2} \mathrm{SO}_{4}(a q)+2 \mathrm{HCN}(g) $$ (c) HCN forms when synthetic fibers containing Orlon \(^{\text {- }}\) or Acrilan \(^{\circledast}\) burn. Acrilan \(^{\circledast}\) has an empirical formula of \(\mathrm{CH}_{2} \mathrm{CHCN},\) so HCN is \(50.9 \%\) of the formula by mass. A rug measures \(3.5 \times 4.5 \mathrm{~m}\) and contains $850 \mathrm{~g}\( of Acrilan \)^{\circledast}$ fibers per square yard of carpet. If the rug burns, will a lethal dose of HCN be generated in the room? Assume that the yield of HCN from the fibers is \(20 \%\) and that the carpet is \(50 \%\) consumed.
When benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\) reacts with bromine \(\left(\mathrm{Br}_{2}\right),\) bromobenzene $\left(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{Br}\right)$ is obtained: $$ \mathrm{C}_{6} \mathrm{H}_{6}+\mathrm{Br}_{2} \longrightarrow \mathrm{C}_{6} \mathrm{H}_{5} \mathrm{Br}+\mathrm{HBr} $$ (a) When \(30.0 \mathrm{~g}\) of benzene reacts with \(65.0 \mathrm{~g}\) of bromine, what is the theoretical yield of bromobenzene? (b) If the actual yield of bromobenzene is \(42.3 \mathrm{~g}\), what is the percentage yield?
A method used by the U.S. Environmental Protection Agency (EPA) for determining the concentration of ozone in air is to pass the air sample through a "bubbler" containing sodium iodide, which removes the ozone according to the following equation: $\mathrm{O}_{3}(g)+2 \mathrm{NaI}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow$ $$ \mathrm{O}_{2}(g)+\mathrm{I}_{2}(s)+2 \mathrm{NaOH}(a q) $$ (a) How many moles of sodium iodide are needed to remove $5.95 \times 10^{-6} \mathrm{~mol}\( of \)\mathrm{O}_{3} ?(\mathbf{b})$ How many grams of sodium iodide are needed to remove \(1.3 \mathrm{mg}\) of \(\mathrm{O}_{3}\) ?
If Avogadro's number of pennies is divided equally among the 321 million men, women, and children in the United States, how many dollars would each receive? How does this compare with the gross domestic product (GDP) of the United States, which was \(\$ 17.419\) trillion in \(2015 ?\) (The GDP is the total market value of the nation's goods and services.)
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