(a) Define the terms limiting reactant and excess reactant. (b) Why are the amounts of products formed in a reaction determined only by the amount of the limiting reactant? (c) Why should you base your choice of which compound is the limiting reactant on its number of initial moles, not on its initial mass in grams?

Short Answer

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(a) The limiting reactant is the reactant that runs out first in a chemical reaction, causing the reaction to stop and not produce more products. The excess reactant is the reactant present in a greater quantity than necessary for the stoichiometric balance and remains partially unused when the reaction is completed. (b) The limiting reactant determines the amount of product formed in a reaction because once it is consumed, the reaction stops, and no more product can be formed. The reaction requires the presence of all reactants in their stoichiometric quantities for it to occur. (c) The choice of the limiting reactant should be based on the number of initial moles because the stoichiometry of a reaction depends on the mole ratios of the reactants, not on their masses. Using initial moles enables calculations of mole ratios directly from the balanced chemical equation and helps determine which reactant will run out first, leading to the correct identification of the limiting reactant. The initial mass in grams may not provide accurate information about the reactant's stoichiometry within the reaction, while the number of initial moles does.

Step by step solution

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a) Limiting and Excess Reactants Definitions

The limiting reactant is the reactant that runs out first in a chemical reaction. Due to this, the reaction stops and cannot produce more products. On the other hand, the excess reactant is the reactant present in a greater quantity than necessary for the stoichiometric balance. It remains partially unused when the reaction is completed.
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b) Role of Limiting Reactant in Product Formation

The limiting reactant determines the amount of product formed in a reaction because once it is consumed, the reaction stops and no more product can be formed. This is due to the fact that all reactants must be present in their stoichiometric quantities for the reaction to occur. If one of the reactants runs out, the reaction will cease to occur, and the product generation will be limited by the amount of the limiting reactant.
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c) Choosing the Limiting Reactant Based on Initial Moles

The choice of the limiting reactant should be based on the number of initial moles because the stoichiometry of a reaction depends on the mole ratios of the reactants, not on their masses. Using the initial moles of a substance allows you to calculate the mole ratios directly from the balanced chemical equation and helps in determining which reactant will run out first, leading to the correct identification of the limiting reactant. The initial mass in grams may not provide accurate information about the reactant's stoichiometry within the reaction, while the number of initial moles does.

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