Chapter 5: Problem 100
An aluminum can of a soft drink is placed in a freezer. Later, you find that the can is split open and its contents have frozen. Work was done on the can in splitting it open. Where did the energy for this work come from?
Chapter 5: Problem 100
An aluminum can of a soft drink is placed in a freezer. Later, you find that the can is split open and its contents have frozen. Work was done on the can in splitting it open. Where did the energy for this work come from?
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Get started for freeConsider two solutions, the first being \(50.0 \mathrm{~mL}\) of $1.00 \mathrm{M} \mathrm{CuSO}_{4}\( and the second \)50.0 \mathrm{~mL}\( of \)2.00 \mathrm{M} \mathrm{KOH} .$ When the two solutions are mixed in a constant-pressure calorimeter, a precipitate forms and the temperature of the mixture rises from 21.5 to \(27.7^{\circ} \mathrm{C} .(\mathbf{a})\) Before mixing, how many grams of Cu are present in the solution of \(\mathrm{CuSO}_{4}\) ? (b) Predict the identity of the precipitate in the reaction. (c) Write complete and net ionic equations for the reaction that occurs when the two solutions are mixed. \((\mathbf{d})\) From the calorimetric data, calculate \(\Delta H\) for the reaction that occurs on mixing. Assume that the calorimeter absorbs only a negligible quantity of heat, that the total volume of the solution is \(100.0 \mathrm{~mL},\) and that the specific heat and density of the solution after mixing are the same as those of pure water.
The complete combustion of methane, \(\mathrm{CH}_{4}(g)\), to form \(\mathrm{H}_{2} \mathrm{O}(l)\) and \(\mathrm{CO}_{2}(g)\) at constant pressure releases \(890 \mathrm{~kJ}\) of heat per mole of \(\mathrm{CH}_{4}\). (a) Write a balanced thermochemical equation for this reaction. (b) Draw an enthalpy diagram for the reaction.
It is estimated that the net amount of carbon dioxide fixed by photosynthesis on the landmass of Earth is \(5.5 \times 10^{16} \mathrm{~g} / \mathrm{yr}\) of \(\mathrm{CO}_{2}\). Assume that all this carbon is converted into glucose. (a) Calculate the energy stored by photosynthesis on land per year, in kJ. (b) Calculate the average rate of conversion of solar energy into plant energy in megawatts, MW \((1 \mathrm{~W}=1 \mathrm{~J} / \mathrm{s}) .\) A large nuclear power plant produces about \(10^{3} \mathrm{MW}\). The energy of how many such nuclear power plants is equivalent to the solar energy conversion?
Identify the force present and explain whether work is being (a) You lift a book off the top performed in the following cases: of a desk. (b) Air is compressed in a bicycle pump.
During a deep breath, our lungs expand about \(2.0 \mathrm{~L}\) against an external pressure of \(101.3 \mathrm{kPa}\). How much work is involved in this process (in J)?
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