Chapter 5: Problem 23
(a) According to the first law of thermodynamics, what quantity is conserved? (b) What is meant by the internal energy of a system? (c) By what means can the internal energy of a closed system increase?
Chapter 5: Problem 23
(a) According to the first law of thermodynamics, what quantity is conserved? (b) What is meant by the internal energy of a system? (c) By what means can the internal energy of a closed system increase?
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Get started for freeAssume that 2 moles of water are formed according to the following reaction at constant pressure \((101.3 \mathrm{kPa})\) and constant temnerature $(298 \mathrm{~K});$ $$ 2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(l) $$ (a) Calculate the pressure-volume work for this reaction. (b) Calculate \(\Delta E\) for the reaction using your answer to (a).
Without doing any calculations, predict the sign of \(\Delta H\) for each of the following reactions: (a) \(2 \mathrm{NO}_{2}(g) \longrightarrow \mathrm{N}_{2} \mathrm{O}_{4}(g)\) (b) \(2 \mathrm{~F}(g) \longrightarrow \mathrm{F}_{2}(g)\) (c) $\mathrm{Mg}^{2+}(g)+2 \mathrm{Cl}^{-}(g) \longrightarrow \mathrm{MgCl}_{2}(s)$ (d) \(\mathrm{HBr}(g) \longrightarrow \mathrm{H}(g)+\mathrm{Br}(g)\)
Consider a system consisting of the following apparatus, in which gas is confined in one flask and there is a vacuum in the other flask. The flasks are separated by a valve. Assume that the flasks are perfectly insulated and will not allow the flow of heat into or out of the flasks to the surroundings. When the valve is opened, gas flows from the filled flask to the evacuated one. (a) Is work performed during the expansion of the gas? (b) Why or why not? (c) Can you determine the value of \(\Delta E\) for the process?
A sodium ion, \(\mathrm{Na}^{+}\), with a charge of $1.6 \times 10^{-19} \mathrm{C}\( and a chloride ion, \)\mathrm{Cl}^{-}\(, with charge of \)-1.6 \times 10^{-19} \mathrm{C}\(, are separated by a distance of \)0.50 \mathrm{nm}$. How much work would be required to increase the separation of the two ions to an infinite distance?
Under constant-volume conditions, the heat of combustion of sucrose \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)\) is $16.49 \mathrm{~kJ} / \mathrm{g}\(. A \)3.00-\mathrm{g}$ sample of sucrose is burned in a bomb calorimeter. The temperature of the calorimeter increases from 21.94 to \(24.62^{\circ} \mathrm{C} .(\mathbf{a})\) What is the total heat capacity of the calorimeter? (b) If the size of the sucrose sample had been exactly twice as large, what would the temperature change of the calorimeter have been?
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