(a) What is meant by the term standard conditions with reference to enthalpy changes? (b) What is meant by the term enthalpy of formation? (c) What is meant by the term standard enthalpy of formation?

Short Answer

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(a) The term standard conditions with reference to enthalpy changes refers to specific reference conditions used to report and compare the values of thermodynamic properties like enthalpy changes. These conditions typically include a pressure of 100 kPa (1 bar), a temperature of \(298.15\ K\) (25°C), and sometimes mention the concentration of the reactants and products as 1 M and partial pressures of gaseous substances as 1 atm. (b) Enthalpy of formation, or heat of formation, refers to the change in enthalpy during the formation of 1 mole of a substance from its constituent elements in their most stable forms. It is the energy change associated with the production of a compound from its basic elements and can be calculated as \(ΔH_f = H_{products} - H_{reactants}\). (c) The standard enthalpy of formation, denoted as \(ΔH^⦵_f\), refers to the enthalpy change occurring when one mole of a substance is formed from its elemental components under standard conditions. It allows for the calculation of overall enthalpy changes for any chemical reaction using the known standard enthalpies of formation for each reactant and product involved in the reaction, according to Hess's law.

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a) Standard conditions with reference to enthalpy changes

Standard conditions, also known as standard state conditions, are specific reference conditions used by chemists and engineers to report and compare the values of various thermodynamic properties like enthalpy changes, Gibbs free energy, and equilibrium constants. These standard conditions typically include a pressure of 100 kPa (1 bar) and a temperature of \(298.15\ K\) (25°C). However, sometimes standard conditions also mention the concentration of the reactants and products as 1 M, and the partial pressures of the gaseous substances as 1 atm. In the context of enthalpy changes, standard conditions provide a common basis for comparing different reactions and their associated energy changes, making it easier to interpret and predict the outcomes of chemical processes.
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b) Enthalpy of formation

Enthalpy of formation, also known as the heat of formation, refers to the change in enthalpy that occurs during the formation of 1 mole of a substance from its constituent elements in their most stable forms (under standard conditions). In other words, it is the energy change associated with the production of a compound from its basic elements. Mathematically, the enthalpy of formation, denoted as \(ΔH_f\) is given by the equation: \[ΔH_f = H_{products} - H_{reactants}\] Where \(ΔH_f\) is the enthalpy of formation, \(H_{products}\) is the enthalpy of the products, and \(H_{reactants}\) is the enthalpy of the reactants.
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c) Standard enthalpy of formation

The standard enthalpy of formation, denoted as \(ΔH^⦵_f\), refers to the enthalpy change that occurs when one mole of a substance is formed from its elemental components under standard conditions. It is essentially the enthalpy of formation measured at the specified standard state conditions to ensure consistency and comparability between different reactions and substances. The standard enthalpy of formation allows us to calculate the overall enthalpy changes for any chemical reaction using the known standard enthalpies of formation for each reactant and product involved in the reaction. This is often known as the Hess's law, which states that the total enthalpy change for a reaction is independent of the reaction path, and can be calculated using the known standard enthalpies of formation.

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