Chapter 7: Problem 18
Arrange the following atoms in order of increasing effective nuclear charge experienced by the electrons in the \(n=2\) shell: Be, Br, Na, P, Se.
Chapter 7: Problem 18
Arrange the following atoms in order of increasing effective nuclear charge experienced by the electrons in the \(n=2\) shell: Be, Br, Na, P, Se.
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Get started for freeOne way to measure ionization energies is ultraviolet photoelectron spectroscopy (PES), a technique based on the photoelectric effect. exo (Section 6.2 ) In PES, monochromatic light is directed onto a sample, causing electrons to be emitted. The kinetic energy of the emitted electrons is measured. The difference between the energy of the photons and the kinetic energy of the electrons corresponds to the energy needed to remove the electrons (that is, the ionization energy). Suppose that a PES experiment is performed in which mercury vapor is irradiated with ultraviolet light of wavelength \(58.4 \mathrm{nm} .\) (a) What is the energy of a photon of this light, in joules? (b) Write an equation that shows the process corresponding to the first ionization energy of \(\mathrm{Hg}\). (c) The kinetic energy of the emitted electrons is measured to be \(1.72 \times 10^{-18} \mathrm{~J}\). What is the first ionization energy of \(\mathrm{Hg}\), in $\mathrm{kJ} / \mathrm{mol} ?$ (d) Using Figure 7.10 , determine which of the halogen elements has a first ionization energy closest to that of mercury.
Write a balanced equation for the reaction that occurs in each of the following cases: (a) Lithium is added to water. (b) Calcium is added to water. (c) Potassium reacts with chlorine gas. (d) Rubidium reacts with oxygen.
(a) Why is calcium generally more reactive than beryllium? (b) Why is calcium generally less reactive than rubidium?
The first ionization energy of the oxygen molecule is the energy required for the following process: $$ \mathrm{O}_{2}(g) \longrightarrow \mathrm{O}_{2}{ }^{+}(g)+\mathrm{e}^{-} $$ The energy needed for this process is \(1175 \mathrm{~kJ} / \mathrm{mol}\), very similar to the first ionization energy of Xe. Would you expect \(\mathrm{O}_{2}\) to react with \(\mathrm{F}_{2}\) ? If so, suggest a product or products of this reaction.
Consider the isoelectronic ions \(\mathrm{Cl}^{-}\) and \(\mathrm{K}^{+}\). (a) Which ion is smaller? (b) Using Equation 7.1 and assuming that core electrons contribute 1.00 and valence electrons contribute nothing to the screening constant, \(S,\) calculate \(Z_{\text {eff }}\) for these two ions. (c) Repeat this calculation using Slater's rules to estimate the screening constant, $S .(\mathbf{d})$ For isoelectronic ions, how are effective nuclear charge and ionic radius related?
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