An element X reacts with oxygen to form \(\mathrm{XO}_{2}\) and with chlorine to form \(\mathrm{XCl}_{4} . \mathrm{XO}_{2}\) is a white solid that melts at high temperatures (above \(1000^{\circ} \mathrm{C}\) ). Under usual conditions, \(\mathrm{XCl}_{4}\) is a colorless liquid with a boiling point of $58^{\circ} \mathrm{C}$. (a) \(\mathrm{XCl}_{4}\) reacts with water to form \(\mathrm{XO}_{2}\) and another product. What is the likely identity of the other product? (b) Do you think that element \(\mathrm{X}\) is a metal, nonmetal, or metalloid? (c) By using a sourcebook such as the CRC Handbook of Chemistry and Physics, try to determine the identity of element X.

Short Answer

Expert verified
The other product formed when XCl₄ reacts with water is hydrochloric acid (HCl). Element X is likely a nonmetal or a metalloid, and the most probable identity of element X is Silicon (Si).

Step by step solution

01

(a) Determine the other product formed when XCl₄ reacts with water.

The given information is that XCl₄ reacts with water to form XO₂ and another product. In general, when a compound with a halogen (such as chlorine) reacts with water, one of the products is a hydrogen halide. Therefore, we can write the reaction as follows: \(XCl_{4} + H_{2}O \longrightarrow XO_{2} + 4H^{+} + 4Cl^{-}\) The other product formed is hydrochloric acid (HCl). The balanced equation for the reaction is: \(XCl_{4} + 4H_{2}O \longrightarrow XO_{2} + 4HCl\)
02

(b) Identify if element X is a metal, nonmetal, or metalloid.

We know that XO₂ is a white solid with a high melting point and XCl₄ is a colorless liquid with a boiling point of 58°C. Based on these properties, we can deduce the following: - XO₂ has a high melting point, which is indicative of a compound with strong ionic or covalent bonding. High melting points are usually observed in ionic compounds of metals and nonmetals or covalent compounds of nonmetals. - XCl₄ is a liquid at room temperature, which implies that it has relatively weak intermolecular forces, consistent with covalent bonds. This suggests that X is a nonmetal or a metalloid. Considering the properties of XO₂ and XCl₄ and the fact that X has a valence of +4, we can conclude that element X is likely a nonmetal or a metalloid.
03

(c) Determine the identity of element X.

Referring to a sourcebook such as the CRC Handbook of Chemistry and Physics, we can find elements that tend to form compounds with a +4 valence state and examine their properties. Possible candidates include: - Tin (Sn): Forms SnO₂ and SnCl₄; however, Sn is a metal, and we deduced that X is likely a nonmetal or metalloid. - Silicon (Si): Forms SiO₂ and SiCl₄. Silicon is a metalloid and has properties consistent with the unknown element X. Based on this information, the identity of element X is likely Silicon (Si).

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Most popular questions from this chapter

Consider the stable elements through lead \((Z=82) .\) In how many instances are the atomic weights of the elements out of order relative to the atomic numbers of the elements?

Some metal oxides, such as \(\mathrm{Sc}_{2} \mathrm{O}_{3},\) do not react with pure water, but they do react when the solution becomes either acidic or basic. Do you expect \(\mathrm{Sc}_{2} \mathrm{O}_{3}\) to react when the solution becomes acidic or when it becomes basic? Write a balinced chemical equation to support vour answer.

Discussing this chapter, a classmate says, "Since elements that form cations are metals and elements that form anions are nonmetals, elements that do not form ions are metalloids." Do you agree or disagree?

(a) Why does xenon react with fluorine, whereas neon does not? (b) Using appropriate reference sources, look up the bond lengths of Xe-F bonds in several molecules. How do these numbers compare to the bond lengths calculated from the atomic radii of the elements?

Hydrogen is an unusual element because it behaves in some ways like the alkali metal elements and in other ways like nonmetals. Its properties can be explained in part by its electron configuration and by the values for its ionization energy and electron affinity. (a) Explain why the electron affinity of hydrogen is much closer to the values for the alkali elements than for the halogens. (b) Is the following statement true? "Hydrogen has the smallest bonding atomic radius of any element that forms chemical compounds." If not, correct it. If it is, explain in terms of electron configurations. (c) Explain why the ionization energy of hydrogen is closer to the values for the halogens than for the alkali metals. (d) The hydride ion is \(\mathrm{H}^{-}\). Write out the process corresponding to the first ionization energy of the hydride ion. (e) How does the process in part (d) compare to the process for the electron affinity of a neutral hydrogen atom?

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