Chapter 7: Problem 65
Write balanced equations for the following reactions: (a) boron trichloride with water, (b) cobalt (II) oxide with nitric acid, (c) phosphorus pentoxide with water, (d) carbon dioxide with aqueous barium hydroxide.
Chapter 7: Problem 65
Write balanced equations for the following reactions: (a) boron trichloride with water, (b) cobalt (II) oxide with nitric acid, (c) phosphorus pentoxide with water, (d) carbon dioxide with aqueous barium hydroxide.
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Get started for freeThe following observations are made about two hypothetical elements \(\mathrm{A}\) and \(\mathrm{B}:\) The \(\mathrm{A}-\mathrm{A}\) and \(\mathrm{B}-\mathrm{B}\) bond lengths in the elemental forms of \(\mathrm{A}\) and \(\mathrm{B}\) are 236 and \(194 \mathrm{pm}\), respectively. A and \(B\) react to form the binary compound \(A B_{2}\), which has a linear structure (that is \(\left.\angle \mathrm{B}-\mathrm{A}-\mathrm{B}=180^{\circ}\right) .\) Based on these statements, predict the separation between the two B nuclei in a molecule of \(\mathrm{AB}_{2}\).
Chlorine reacts with oxygen to form \(\mathrm{Cl}_{2} \mathrm{O}_{7} .\) (a) What is the name of this product (see Table 2.6)? (b) Write a balanced equation for the formation of \(\mathrm{Cl}_{2} \mathrm{O}_{7}(l)\) from the elements. (c) Would you expect \(\mathrm{Cl}_{2} \mathrm{O}_{7}\) to be more reactive toward \(\mathrm{H}^{+}(a q)\) or \(\mathrm{OH}^{-}(a q) ?(\mathbf{d})\) If the oxygen in \(\mathrm{Cl}_{2} \mathrm{O}_{7}\) is considered to have the -2 oxidation state, what is the oxidation state of the \(\mathrm{Cl}\) ? What is the electron configuration of \(\mathrm{Cl}\) in this oxidation state?
Based on their positions in the periodic table, predict which atom of the following pairs will have the smaller first ionization energy: (a) $\mathrm{Br}, \mathrm{Kr} ; \mathbf{( b )} \mathrm{C}, \mathrm{Ca} ;(\mathbf{c}) \mathrm{Li}, \mathrm{Rb} ;\(; (d) \)\mathrm{Pb}, \mathrm{Si} ;$ (e) \(\mathrm{Al}, \mathrm{B}\).
Give examples of transition metal ions with +3 charge that have an electron configuration of \(n d^{5}(n=3,4,5 \ldots)\).
It is possible to define metallic character as we do in this book and base it on the reactivity of the element and the ease with which it loses electrons. Alternatively, one could measure how well electricity is conducted by each of the elements to determine how "metallic" the elements are. On the basis of conductivity, there is not much of a trend in the periodic table: Silver is the most conductive metal, and manganese the least. Look up the first ionization energies of silver and manganese; which of these two elements would you call more metallic based on the way we define it in this book?
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