Identify \(a+2\) cation that has the following ground state electron configurations: (a) \([\mathrm{Ne}]\) (b) \([\mathrm{Ar}] 3 d^{9}\) (c) \([\mathrm{Xe}] 4 f^{14} 5 d^{10} 6 s^{2}\)

Short Answer

Expert verified
The \(a+2\) cations for each case are: (a) None (b) \(Cu^{2+}\) (c) \(Hg^{2+}\)

Step by step solution

01

Case (a) \([\mathrm{Ne}]\)

Refer to the periodic table and find the element with the electron configuration \([\mathrm{Ne}]\). In this case, Neon's electron configuration is the same as the ground state electron configuration in question. The electron configuration of neutral Neon (Ne) is \(1s^2 2s^2 2p^6\), which is also represented as \([\mathrm{Ne}]\). For an \(a+2\) cation state, we need to consider removing two electrons from the outermost shell. However, considering the full electron configuration of neon, there are no outer electrons for the \(a+2\) cation. Thus, there is no valid \(a+2\) cation for case (a).
02

Case (b) \([\mathrm{Ar}] 3 d^{9}\)

First, let's find the element with the given ground state electron configuration. The electron configuration of neutral Argon (Ar) is \(1s^2 2s^2 2p^6 3s^2 3p^6\), which can be represented as \([\mathrm{Ar}]\). Now, consider adding the \(3d^9\) configuration to argon, making the electron configuration \([\mathrm{Ar}] 3d^9\). This results in the element, Copper (Cu) with a neutral electron configuration of \(1s^2 2s^2 2p^6 3s^2 3p^6 3d^{10} 4s^1\). For an \(a+2\) cation, we need to remove two electrons from the outermost shell. In this case, we will remove the 4s electrons and then remove 1 of the 3d electrons. Doing this, the electron configuration of the \(a+2\) cation for copper will be \([\mathrm{Ar}] 3d^{9}\). The \(a+2\) cation for case (b) is \(Cu^{2+}\).
03

Case (c) \([\mathrm{Xe}] 4 f^{14} 5 d^{10} 6 s^{2}\)

First, let's find the element with the given ground state electron configuration. The electron configuration of neutral Xenon (Xe) is \(1s^2 2s^2 2p^6 3s^2 3p^6 3d^{10} 4s^2 4p^6 4d^{10} 5s^2 5p^6\), which can be represented as \([\mathrm{Xe}]\). Now, consider adding the \(4f^{14}\), \(5d^{10}\), and \(6s^2\) configurations to xenon, making the electron configuration \([\mathrm{Xe}] 4f^{14} 5d^{10} 6s^2\). This results in the element, Mercury (Hg) with a neutral electron configuration of \(1s^2 2s^2 2p^6 3s^2 3p^6 3d^{10} 4s^2 4p^6 4d^{10} 5s^2 5p^6 4f^{14} 5d^{10} 6s^2\). For an \(a+2\) cation, we need to remove two electrons from the outermost shell. In this case, we will remove the 6s electrons. Doing this, the electron configuration of the \(a+2\) cation for mercury will be \([\mathrm{Xe}] 4f^{14} 5d^{10}\). The \(a+2\) cation for case (c) is \(Hg^{2+}\).

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Most popular questions from this chapter

Based on their positions in the periodic table, predict which atom of the following pairs will have the smaller first ionization energy: (a) $\mathrm{Br}, \mathrm{Kr} ; \mathbf{( b )} \mathrm{C}, \mathrm{Ca} ;(\mathbf{c}) \mathrm{Li}, \mathrm{Rb} ;\(; (d) \)\mathrm{Pb}, \mathrm{Si} ;$ (e) \(\mathrm{Al}, \mathrm{B}\).

(a) As described in Section 7.7, the alkali metals react with hydrogen to form hydrides and react with halogens to form halides. Compare the roles of hydrogen and halogens in these reactions. Write balanced equations for the reaction of fluorine with calcium and for the reaction of hydrogen with calcium. (b) What is the oxidation number and electron configuration of calcium in each product?

(a) What is the general relationship between the size of an atom and its first ionization energy? (b) Which element in the periodic table has the largest ionization energy? Which has the smallest?

Detailed calculations show that the value of \(Z_{\text {eff }}\) for the outermost electrons in \(\mathrm{Si}\) and \(\mathrm{Cl}\) atoms is \(4.29+\) and \(6.12+,\) respectively. (a) What value do you estimate for \(Z_{\text {eff }}\) experienced by the outermost electron in both Si and Cl by assuming core electrons contribute 1.00 and valence electrons contribute 0.00 to the screening constant? (b) What values do you estimate for \(Z_{\text {eff }}\) using Slater's rules? (c) Which approach gives a more accurate estimate of \(Z_{\text {eff }} ?\) (d) Which method of approximation more accurately accounts for the steady increase in \(Z_{\text {eff }}\) that occurs upon moving left to right across a period? (e) Predict \(Z_{\text {eff }}\) for a valence electron in P, phosphorus, based on the calculations for \(\mathrm{Si}\) and \(\mathrm{Cl}\).

(a) Why does xenon react with fluorine, whereas neon does not? (b) Using appropriate reference sources, look up the bond lengths of Xe-F bonds in several molecules. How do these numbers compare to the bond lengths calculated from the atomic radii of the elements?

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