Chapter 8: Problem 11
Consider the element silicon, Si. (a) Write its electron configuration. (b) How many valence electrons does a silicon atom have? (c) Which subshells hold the valence electrons?
Chapter 8: Problem 11
Consider the element silicon, Si. (a) Write its electron configuration. (b) How many valence electrons does a silicon atom have? (c) Which subshells hold the valence electrons?
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Get started for freeA major challenge in implementing the "hydrogen economy" is finding a safe, lightweight, and compact way of storing hydrogen for use as a fuel. The hydrides of light metals are attractive for hydrogen storage because they can store a high weight percentage of hydrogen in a small volume. For example, \(\mathrm{NaAlH}_{4}\) can release \(5.6 \%\) of its mass as \(\mathrm{H}_{2}\) upon decomposing to \(\mathrm{NaH}(s), \mathrm{Al}(s),\) and $\mathrm{H}_{2}(g) . \mathrm{NaAlH}_{4}$ possesses both covalent bonds, which hold polyatomic anions together, and ionic bonds. (a) Write a balanced equation for the decomposition of \(\mathrm{NaAlH}_{4}\). (b) Which element in \(\mathrm{NaAlH}_{4}\) is the most electronegative? Which one is the least electronegative? (c) Based on electronegativity differences, predict the identity of the polyatomic anion. Draw a Lewis structure for this ion. (d) What is the formal charge on hydrogen in the polyatomic ion?
(a) Draw the Lewis structure for hydrogen peroxide, $\mathrm{H}_{2} \mathrm{O}_{2}$. (b) What is the weakest bond in hydrogen peroxide? (c) Hydrogen peroxide is sold commercially as an aqueous solution in brown bottles to protect it from light. Calculate the longest wavelength of light that has sufficient energy to break the weakest bond in hydrogen peroxide.
Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, $\mathrm{H}_{2} \mathrm{PO}_{4}^{-},\( in which the \)\mathrm{H}$ atoms are bonded to \(\mathrm{O}\) atoms. (a) What is the predicted dominant Lewis structure if satisfying the octet rule is the top criterion? (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?
True or false: \((\mathbf{a})\) The \(\mathrm{C}-\mathrm{C}\) bonds in benzene are all the same length and correspond to typical single \(\mathrm{C}-\mathrm{C}\) bond lengths. (b) The \(\mathrm{C}-\mathrm{C}\) bond in acetylene, \(\mathrm{HCCH}\), is longer than the average \(\mathrm{C}-\mathrm{C}\) bond length in benzene.
We can define average bond enthalpies and bond lengths for ionic bonds, just like we have for covalent bonds. Which ionic bond is predicted to have the smaller bond enthalpy, \(\mathrm{Li}-\mathrm{F}\) or \(\mathrm{Cs}-\mathrm{F}\) ?
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