Chapter 8: Problem 18
Which ionic compound is expected to form from combining the following pairs of elements? (a) calcium and nitrogen, (b) cesium and bromine, (c) strontium and sulfur, (d) aluminum and selenium.
Chapter 8: Problem 18
Which ionic compound is expected to form from combining the following pairs of elements? (a) calcium and nitrogen, (b) cesium and bromine, (c) strontium and sulfur, (d) aluminum and selenium.
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Get started for freeAlthough \(\mathrm{I}_{3}^{-}\) is a known ion, \(\mathrm{F}_{3}^{-}\) is not. \((\mathbf{a})\) Draw the Lewis structure for \(I_{3}^{-}\) (it is linear, not a triangle). (b) One of your classmates says that \(\mathrm{F}_{3}^{-}\) does not exist because \(\mathrm{F}\) is too electronegative to make bonds with another atom. Give an example that proves your classmate is wrong. (c) Another classmate says \(\mathrm{F}_{3}^{-}\) does not exist because it would violate the octet rule. Is this classmate possibly correct? (d) Yet another classmate says \(\mathrm{F}_{3}^{-}\) does not exist because \(\mathrm{F}\) is too small to make bonds to more than one atom. Is this classmate possibly correct?
(a) Does the lattice energy of an ionic solid increase or decrease (i) as the charges of the ions increase, (ii) as the sizes of the ions increase? (b) Arrange the following substances not listed in Table 8.1 according to their expected lattice energies, listing them from lowest lattice energy to the highest: MgS, KI, GaN, LiBr.
In the following pairs of binary compounds, determine which one is a molecular substance and which one is an ionic substance. Use the appropriate naming convention (for ionic or molecular substances) to assign a name to each compound: (a) \(\mathrm{SiF}_{4}\) and \(\mathrm{LaF}_{3}\), (b) \(\mathrm{FeCl}_{2}\) and \(\mathrm{ReCl}_{6}\), (c) \(\mathrm{PbCl}_{4}\) and RbCl.
(a) The nitrate ion, \(\mathrm{NO}_{3}^{-}\), has a trigonal planar structure with the \(\mathrm{N}\) atom as the central atom. Draw the Lewis structure(s) for the nitrate ion. (b) Given \(S=\mathrm{O}\) and \(\mathrm{S}-\mathrm{O}\) bond lengths are \(158 \mathrm{pm}\) and \(143 \mathrm{pm}\) respectively, estimate the sulphuroxygen bond distances in the ion.
(a) Use Lewis symbols to represent the reaction that occurs between Li and O atoms. (b) What is the chemical formula of the most likely product? (c) How many electrons are transferred? (d) Which atom loses electrons in the reaction?
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