Which of these elements are unlikely to form ionic bonds? $\mathrm{Mg}, \mathrm{Al}, \mathrm{Si}, \mathrm{Br}, \mathrm{I}$.

Short Answer

Expert verified
Al, Si, and I are unlikely to form ionic bonds with the other given elements, as their electronegativity differences with the other elements are lower than the threshold typically required for ionic bond formation.

Step by step solution

01

Identify metals and non-metals

In the given elements, Mg and Al are metals, while Si, Br, and I are non-metals.
02

Calculate electronegativity differences

For the formation of ionic bonds, a high electronegativity difference between elements is expected. Ionic bonding occurs with an electronegativity difference of around 1.7 or more. The electronegativity values for the given elements are: - Mg: 1.31 - Al: 1.61 - Si: 1.90 - Br: 2.96 - I: 2.66
03

Assess electrostatic attractions

We can use electronegativity differences to estimate the likelihood of electrostatic attraction between elements: 1. Mg & Al: \(|1.31 - 1.61| = 0.3\) 2. Mg & Si: \(|1.31 - 1.90| = 0.59\) 3. Mg & Br: \(|1.31 - 2.96| = 1.65\) 4. Mg & I: \(|1.31 - 2.66| = 1.35\) 5. Al & Si: \(|1.61 - 1.90| = 0.29\) 6. Al & Br: \(|1.61 - 2.96| = 1.35\) 7. Al & I: \(|1.61 - 2.66| = 1.05\) 8. Si & Br: \(|1.90 - 2.96| = 1.06\) 9. Si & I: \(|1.90 - 2.66| = 0.76\) 10. Br & I: \(|2.66 - 2.96| = 0.3\) Note that the highest electronegativity differences occur when Mg and Br (\(1.65\)), Mg and I (\(1.35\)), Al and Br (\(1.35\)), and Si and Br (\(1.06\)) are paired. However, only the Mg-Br pairing approaches the threshold (\(1.7\)) typically required for ionic bond formation.
04

Identify unlikely candidates for ionic bonding

From the differences in electronegativity, Mg with Br is closest to forming an ionic bond, though it doesn't reach the typical threshold. The other pairings have some similarities (Al-Br and Si-Br), but the electronegativity differences are lower, making them less likely to form ionic bonds. Thus, Al, Si, and I are unlikely to form ionic bonds with the other given elements.

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