Chapter 10: Problem 71
A chemist isolated a gas in a glass bulb with a volume of \(255 \mathrm{~mL}\) at a temperature of \(25.0{ }^{\circ} \mathrm{C}\) and a pressure (in the bulb) of 10.0 torr. The gas weighed \(12.1 \mathrm{mg}\). What is the molar mass of this gas?
Short Answer
Expert verified
The molar mass of the gas is approximately 32.0 g/mol.
Step by step solution
01
Convert Temperature to Kelvin
The temperature needs to be converted from Celsius to Kelvin because all gas law calculations require temperature in Kelvin. To convert it, use the formula: Kelvin = Celsius + 273.15. Thus, the temperature in Kelvin is 25.0 + 273.15.
02
Convert Pressure to Atmospheres
The pressure should also be in standard units, which is atmospheres (atm). To convert torr to atmospheres, use the conversion factor 1 atm = 760 torr. Therefore, the pressure is calculated as 10.0 torr * (1 atm / 760 torr).
03
Convert Volume to Liters
The volume given in milliliters needs to be converted to liters because the ideal gas law uses volume in liters. To convert milliliters to liters, use the conversion factor 1 L = 1000 mL. Thus, the volume in liters is 255 mL * (1 L / 1000 mL).
04
Convert Mass to Grams
The mass of the gas must be in grams for calculating the molar mass. Since the mass is given in milligrams, convert it to grams using 1 gram = 1000 milligrams. Hence, the mass in grams is 12.1 mg * (1 g / 1000 mg).
05
Use the Ideal Gas Law to Find the Number of Moles of Gas
The ideal gas law is given by PV = nRT, where P is the pressure in atmospheres, V is the volume in liters, n is the number of moles, R is the ideal gas constant (0.0821 L*atm/(mol*K)), and T is the temperature in Kelvin. Solving for n gives n = (PV) / (RT).
06
Calculate the Molar Mass of the Gas
Molar mass (M) is equal to the mass of the gas in grams (m) divided by the number of moles (n). Using the mass from Step 4 and the moles from Step 5, calculate the molar mass with the formula M = m / n.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Understanding the Ideal Gas Law
The ideal gas law is a crucial equation in the field of chemistry and physics, providing a practical relationship between pressure (P), volume (V), temperature (T), and the amount of substance in moles (n) for an ideal gas. The law is articulated through the equation:
\( PV = nRT \)
where R is the ideal gas constant. In this scenario, we leverage the ideal gas law to determine the number of moles of a gas given its pressure, volume, and temperature.
To apply the ideal gas law correctly, it’s imperative that all units are consistent. Pressure should be in atmospheres, volume in liters, temperature in Kelvin, and R must match these units. In our exercise, after converting each measurement to the requisite units, we rearrange the formula to solve for the number of moles (n):
\( n = \frac{PV}{RT} \)
Utilizing the ideal gas law requires a precise grasp of various units and conversion, making it a perfect example of how diverse concepts in chemistry are intertwined.
\( PV = nRT \)
where R is the ideal gas constant. In this scenario, we leverage the ideal gas law to determine the number of moles of a gas given its pressure, volume, and temperature.
To apply the ideal gas law correctly, it’s imperative that all units are consistent. Pressure should be in atmospheres, volume in liters, temperature in Kelvin, and R must match these units. In our exercise, after converting each measurement to the requisite units, we rearrange the formula to solve for the number of moles (n):
\( n = \frac{PV}{RT} \)
Utilizing the ideal gas law requires a precise grasp of various units and conversion, making it a perfect example of how diverse concepts in chemistry are intertwined.
Converting Units in Chemistry
In chemistry, it’s essential to work with a standardized set of units to ensure accurate and coherent computations. This exercise involves multiple conversions across different units of measurement, which is a common practice in the subject.
Pressure, initially presented in torr, was converted to atmospheres using the conversion factor \(1 atm = 760 torr\). Similarly, volume was transformed from milliliters to liters, recognizing that \(1 L = 1000 mL\). Lastly, the mass in milligrams was converted into grams with the conversion factor \(1 g = 1000 mg\).
These conversions are pivotal for the following reasons:
Pressure, initially presented in torr, was converted to atmospheres using the conversion factor \(1 atm = 760 torr\). Similarly, volume was transformed from milliliters to liters, recognizing that \(1 L = 1000 mL\). Lastly, the mass in milligrams was converted into grams with the conversion factor \(1 g = 1000 mg\).
These conversions are pivotal for the following reasons:
- Ensuring consistency with the ideal gas constant’s units.
- Facilitating the application of equations like the ideal gas law.
- Allowing for clear communication of scientific data.
Temperature Conversion to Kelvin
When working with gases and their behaviors under varying conditions, Kelvin is the temperature scale of choice. It’s the SI (International System of Units) unit for thermodynamic temperature and is preferred because it starts at absolute zero, implying there is no negative temperature in Kelvin, which simplifies calculations.
The conversion from Celsius to Kelvin is straightforward and necessary for all gas law problems:
\( K = ^\circ C + 273.15 \)
For our chemist’s gas bulb at a cozy \(25.0{ }^\circ C\), we find the Kelvin temperature to be: \(25.0 + 273.15\). This step is fundamental because the behavior of gases is directly proportional to the temperature in Kelvin, thereby impacting the gas' pressure and volume.
Temperature in Kelvin is a basic yet vital conversion, transitioning from everyday Celsius scale to the one required for theoretical and experimental gas law analysis. Understanding how to perform this conversion is a key skill in tackling thermodynamic problems in chemistry.
The conversion from Celsius to Kelvin is straightforward and necessary for all gas law problems:
\( K = ^\circ C + 273.15 \)
For our chemist’s gas bulb at a cozy \(25.0{ }^\circ C\), we find the Kelvin temperature to be: \(25.0 + 273.15\). This step is fundamental because the behavior of gases is directly proportional to the temperature in Kelvin, thereby impacting the gas' pressure and volume.
Temperature in Kelvin is a basic yet vital conversion, transitioning from everyday Celsius scale to the one required for theoretical and experimental gas law analysis. Understanding how to perform this conversion is a key skill in tackling thermodynamic problems in chemistry.