Chapter 14: Problem 21
State Le Châtelier's principle in your own words.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 14: Problem 21
State Le Châtelier's principle in your own words.
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeAt a certain temperature, \(K_{\mathrm{c}}=0.18\) for the equilibrium $$ \mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g) \rightleftharpoons \mathrm{PCl}_{5}(g) $$ If \(0.026 \mathrm{~mol}\) of \(\mathrm{PCl}_{5}\) is placed in a \(2.00 \mathrm{~L}\) vessel at this temperature, what will the concentration of \(\mathrm{PCl}_{3}\) be at equilibrium?
At \(460^{\circ} \mathrm{C},\) the reaction $$ \mathrm{SO}_{2}(g)+\mathrm{NO}_{2}(g) \rightleftharpoons \mathrm{NO}(g)+\mathrm{SO}_{3}(g) $$ has \(K_{\mathrm{c}}=85.0\). A reaction flask at \(460^{\circ} \mathrm{C}\) contains these gases at the following concentrations: \(\left[\mathrm{SO}_{2}\right]=0.00250 \mathrm{M}\), \(\left[\mathrm{NO}_{2}\right]=0.00350 \quad M,[\mathrm{NO}]=0.0250 \quad M,\) and \(\left[\mathrm{SO}_{3}\right]=0.0400 \mathrm{M}\) (a) Is the reaction at equilibrium? (b) If not, in which direction will the reaction proceed to arrive at equilibrium?
Calculate the molar concentration of water in (a) \(18.0 \mathrm{~mL}\) of \(\mathrm{H}_{2} \mathrm{O}(l),\) (b) \(100.0 \mathrm{~mL}\) of \(\mathrm{H}_{2} \mathrm{O}(l),\) and \(\mathbf{( c )} 1.00 \mathrm{~L}\) of \(\mathrm{H}_{2} \mathrm{O}(l)\). Assume that the density of water is \(1.00 \mathrm{~g} / \mathrm{mL}\)
Le Châtelier's principle qualitatively describes what will occur if a reactant or product is added or removed from a reaction mixture. Describe as many ways as possible to remove a reactant or product from a mixture at equilibrium.
At a certain temperature, \(K_{\mathrm{c}}=4.3 \times 10^{5}\) for the reaction $$ \mathrm{HCO}_{2} \mathrm{H}(g) \rightleftharpoons \mathrm{CO}(g)+\mathrm{H}_{2} \mathrm{O}(g) $$ If \(0.200 \mathrm{~mol}\) of \(\mathrm{HCO}_{2} \mathrm{H}\) is placed in a \(1.00 \mathrm{~L}\) vessel, what will be the concentrations of \(\mathrm{CO}\) and \(\mathrm{H}_{2} \mathrm{O}\) when the system reaches equilibrium? (Hint: Where does the position of equilibrium lie when \(K\) is very large?)
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