Chapter 18: Problem 19
On the basis of our definition of entropy, suggest why entropy is a state function.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 18: Problem 19
On the basis of our definition of entropy, suggest why entropy is a state function.
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeChloroform, formerly used as an anesthetic and now believed to be a carcinogen, has a heat of vaporization \(\Delta H_{\text {vaporization }}=\) \(31.4 \mathrm{~kJ} \mathrm{~mol}^{-1}\). The change, \(\mathrm{CHCl}_{3}(l) \longrightarrow \mathrm{CHCl}_{3}(g)\) has \(\Delta S^{\circ}=94.2 \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}\). At what temperature do we expect \(\mathrm{CHCl}_{3}\) to boil (i.e., at what temperature will liquid and vapor be in equilibrium at 1 atm pressure)?
What are the units of \(P \Delta V\) if pressure is expressed in pascals and volume is expressed in cubic meters?
Considering the fact that the formation of a bond between two atoms is exothermic and is accompanied by an entropy decrease, explain why all chemical compounds decompose into individual atoms if heated to a high enough temperature.
State the second law of thermodynamics.
The value of \(\Delta E\) for a certain change is \(-1455 \mathrm{~J}\). During the change, the system absorbs \(812 \mathrm{~J}\) of heat. Did the system do work, or was work done on the system? How much work, expressed in joules, was involved?
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