Chapter 20: Problem 93
What percentage of cesium chloride made from cesium137 (beta emitter, \(t_{1 / 2}=30.1 \mathrm{y}\) ) remains after \(150 \mathrm{y}\) ? What chemical product forms?
Short Answer
Expert verified
After 150 years, approximately 12.5% of cesium-137 remains, and the chemical product formed is barium-137m.
Step by step solution
01
Understand Half-life Concept
The half-life of a substance is the time it takes for half of the substance to decay into another form. For cesium-137, it has a half-life of 30.1 years, meaning every 30.1 years, half of it decays.
02
Calculate the Number of Half-lives
To find out how many half-lives have passed after 150 years, divide the total time elapsed by the half-life of the substance: Number of half-lives = Total time elapsed / Half-life of the substance = 150 years / 30.1 years per half-life.
03
Use the Half-life Decay Formula
Apply the formula for exponential decay: remaining fraction = \((1/2)^{\text{number of half-lives}}\). This will allow us to calculate the remaining fraction of cesium-137 after 150 years.
04
Determine the Percentage Remaining
Multiply the remaining fraction by 100 to convert it to a percentage. This will give the percentage of cesium-137 that remains after 150 years.
05
Identify the Chemical Product Formed
During the beta decay of cesium-137, it transforms into barium-137m, which is the chemical product formed.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Exponential Decay
Exponential decay is a fundamental concept in understanding the decrease of a quantity over time, especially in contexts like radioactive decay in nuclear chemistry. When an unstable nucleus undergoes radioactive decay, the number of original atoms decreases over time in a manner that can be modeled mathematically by an exponential function. In simple terms, this means that in each equal amount of time, a constant percentage of the remaining substance will decay, rather than a constant number of atoms.
For example, if a radioactive substance has a half-life of 30.1 years, this does not mean that exactly half of the atoms decay every 30.1 years. Rather, it signifies that the probability for each atom to decay within that period is such that, on average, half of the remaining atoms will have decayed by the end of one half-life. This concept is crucial in fields like medicine, archeology, and environmental science, where understanding the decay of substances over time can have significant implications.
For example, if a radioactive substance has a half-life of 30.1 years, this does not mean that exactly half of the atoms decay every 30.1 years. Rather, it signifies that the probability for each atom to decay within that period is such that, on average, half of the remaining atoms will have decayed by the end of one half-life. This concept is crucial in fields like medicine, archeology, and environmental science, where understanding the decay of substances over time can have significant implications.
Beta Emission
Beta emission is one of the main types of radioactive decay. During beta emission, a beta particle, which is a high-speed electron or positron, is ejected from an atomic nucleus. This process occurs because the nucleus has an imbalance of neutrons and protons, and emitting a beta particle is a way for it to reach a more stable state.
In the case of cesium-137, a neutron in its nucleus turns into a proton while releasing an electron (a beta particle) and an antineutrino. This transformation results in a new element with an atomic number that is one higher than the original; cesium-137 becomes barium-137 after it undergoes beta decay. Understanding beta emission is not only key to grasping nuclear reactions but also to applications like radiation therapy and radiometric dating, where the properties of beta particles are utilized.
In the case of cesium-137, a neutron in its nucleus turns into a proton while releasing an electron (a beta particle) and an antineutrino. This transformation results in a new element with an atomic number that is one higher than the original; cesium-137 becomes barium-137 after it undergoes beta decay. Understanding beta emission is not only key to grasping nuclear reactions but also to applications like radiation therapy and radiometric dating, where the properties of beta particles are utilized.
Nuclear Chemistry
Nuclear chemistry is the sub-discipline of chemistry that deals with changes in the nucleus of elements and the energy that is consequently produced or used. This field encompasses the study of both stable and unstable isotopes, helping us to understand processes such as radioactive decay, nuclear fission, and nuclear fusion.
Radioactive isotopes, like cesium-137, are of particular interest as they can be used in various applications, ranging from medical treatments to energy generation in nuclear power plants. The rates at which these isotopes decay, characterized by their specific half-lives, are crucial for managing their use and understanding their impact on the environment. With each half-life, as radioactive isotopes decay, they form new elements, changing the chemical composition of a sample over time—propelling innovations in energy, medicine, and environmental science.
Radioactive isotopes, like cesium-137, are of particular interest as they can be used in various applications, ranging from medical treatments to energy generation in nuclear power plants. The rates at which these isotopes decay, characterized by their specific half-lives, are crucial for managing their use and understanding their impact on the environment. With each half-life, as radioactive isotopes decay, they form new elements, changing the chemical composition of a sample over time—propelling innovations in energy, medicine, and environmental science.