In a report to a supervisor, a chemist described an experiment in the following way: " \(0.0800 \mathrm{~mol}\) of \(\mathrm{H}_{2} \mathrm{O}_{2}\) decomposed into \(0.0800 \mathrm{~mol}\) of \(\mathrm{H}_{2} \mathrm{O}\) and \(0.0400 \mathrm{~mol}\) of \(\mathrm{O}_{2}\)." Express the chemistry and stoichiometry of this reaction by a conventional chemical equation.

Short Answer

Expert verified
The balanced chemical equation is: \(2 H_2O_2 \rightarrow 2 H_2O + O_2\).

Step by step solution

01

Write Down the Original Reactants and Products

Begin by listing the known reactants and products in a chemical reaction. The reactant in this reaction is hydrogen peroxide (H_2O_2) and the products are water (H_2O) and oxygen (O_2).
02

Balance the Hydrogen Atoms

Each side of the chemical equation should have the same number of hydrogen atoms. Since there are 0.0800 mol of H_2O_2 decomposing into 0.0800 mol of H_2O, the hydrogen atoms balance as 2 atoms for each hydrogen peroxide molecule and 2 atoms for each water molecule.
03

Balance the Oxygen Atoms

We must also balance the oxygen atoms. Initially, there are 2 oxygen atoms in H_2O_2, and there should be a total of 2 oxygen atoms in the products for each H_2O_2 molecule that decomposes. Since we have 0.0800 mol of H_2O and 0.0400 mol of O_2, there are a total of (0.0800 mol of H_2O x 1 oxygen atom/mol) + (0.0400 mol of O_2 x 2 oxygen atoms/mol) = 0.0800 + 0.0800 = 0.1600 mol of oxygen atoms in the products.
04

Derive the Balanced Chemical Equation

Considering the stoichiometry based on the moles provided, the balanced chemical equation is:2 H_2O_2 (reactant) decomposes to form2 H_2O(water) plus1 O_2(oxygen gas), because 2 moles of H_2O and 1 mole of O_2 provide the correct amount of oxygen atoms to balance the equation.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Balancing Chemical Equations
The process of balancing chemical equations is fundamental for understanding chemical reactions. To ensure the law of conservation of mass is upheld, one must adjust the coefficients (the numbers in front of the chemical formulas) to have the same number of atoms of each element on both sides of the equation.

Let's consider a straightforward approach if you're faced with a chemical equation to balance. First, write down the unbalanced equation with all reactants and products. From the original statement of our exercise, hydrogen peroxide (H_2O_2) decomposes into water (H_2O) and oxygen gas (O_2), written as: H_2O_2 → H_2O + O_2. Next, count the number of atoms of each element in both reactants and products. If they don't match, you need to adjust the coefficients. For the given reaction, we observe there are two hydrogens on both sides, but we need to balance the oxygens by placing coefficients to indicate that two molecules of hydrogen peroxide yield two molecules of water and one molecule of oxygen gas, which can be represented as: 2H_2O_2 → 2H_2O + O_2.

In this case, the hydrogen atoms and oxygen atoms are balanced, with four hydrogens and four oxygens on both sides of the equation. Remember that coefficients should be the simplest whole numbers that balance the atoms, and modifying subscripts (the small numbers after element symbols) is not allowed as it changes the compound's identity.
Stoichiometric Calculations
Stoichiometric calculations are crucial for quantifying the amounts of reactants and products in a chemical reaction. They are based on the balanced chemical equation and the concept of the mole, which is a standard unit to measure the amount of substance. In the context of the provided exercise, the mole relationship between H_2O_2, H_2O, and O_2 is used to express the stoichiometry.

For the decomposition of hydrogen peroxide, we are initially informed that 0.0800 mol of H_2O_2 decomposes into 0.0800 mol of H_2O and 0.0400 mol of O_2. Using the balanced equation, we can see that for every 2 moles of H_2O_2, there are 2 moles of H_2O and 1 mole of O_2 produced. This perfectly matches the provided mole ratio from the experiment, and you can use it to determine the amount of any reactant or product in the reaction if given the amount of any other substance involved.

Always ensure that your stoichiometric calculations are based on a correctly balanced chemical equation to prevent errors. These calculations can predict how much product will form from a certain amount of reactant (yield) or how much reactant is needed to form a desired amount of product (requirement). Remember that in cases where a reaction does not go to completion or has side reactions, you may also need to consider reaction efficiencies and purities.
Chemical Reaction Representation
Chemical reactions are represented using symbols and formulas to convey the identities of the reactants and products involved in a reaction. This includes the physical states of the substances, which might be indicated by abbreviations such as (s) for solids, (l) for liquids, (g) for gases, and (aq) for aqueous solutions.

In the given decomposition reaction, we might represent the reaction with states included as: 2H_2O_2(l) → 2H_2O(l) + O_2(g). This indicates that liquid hydrogen peroxide decomposes to form liquid water and gaseous oxygen. Such representations provide not only the types of molecules involved but also a visual summary of the process, which is particularly useful when discussing reaction conditions or predicting the behavior of a system under different states.

Apart from the states, it's also important to note other conditions such as temperature, pressure, or the presence of catalysts, which can affect how the reaction proceeds. These conditions are usually written above or below the arrow in a chemical equation. Chemical reaction representations help chemists and students alike to visualize and understand chemical processes and their requirements as clearly as possible.

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Most popular questions from this chapter

The hallucinogenic drug LSD has the molecular formula \(\mathrm{C}_{20} \mathrm{H}_{25} \mathrm{~N}_{3} \mathrm{O} .\) One suspected sample contained \(74.07 \% \mathrm{C},\) \(7.95 \% \mathrm{H},\) and \(9.99 \% \mathrm{~N}\) (a) What is the percentage of \(\mathrm{O}\) in the sample? (b) Are these data consistent for \(L S D ?\)

Lime, \(\mathrm{CaO},\) can be produced in two steps as shown in the equations below. If the percentage yield of the first step is \(83.5 \%\) and the percentage yield of the second step is \(71.4 \%\), what is the expected overall percentage yield for producing \(\mathrm{CaO}\) from \(\mathrm{CaCl}_{2} ?\) $$ \begin{aligned} \mathrm{CaCl}_{2}(a q)+\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O} \longrightarrow \mathrm{CaCO}_{3}(s)+2 \mathrm{HCl}(a q) \\ \mathrm{CaCO}_{3}(s) \stackrel{\text { heat }}{\longrightarrow} \mathrm{CaO}(s)+\mathrm{CO}_{2}(g) \end{aligned} $$

How many moles of \(S\) are needed to combine with 0.225 mol Al to give \(\mathrm{Al}_{2} \mathrm{~S}_{3}\) ?

How many atoms are in \(1.50 \mathrm{~mol}\) of carbon-12? How many grams does this much carbon-12 weigh?

Aluminum sulfate can be made by the following reaction. \(2 \mathrm{AlCl}_{3}(a q)+3 \mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}(a q)+6 \mathrm{HCl}(a q)\) It is quite soluble in water, so to isolate it the solution has to be evaporated to dryness. This drives off the volatile \(\mathrm{HCl},\) but the residual solid has to be heated to a little over \(200^{\circ} \mathrm{C}\) to drive off all of the water. In one experiment, \(25.0 \mathrm{~g}\) of \(\mathrm{AlCl}_{3}\) was mixed with \(30.0 \mathrm{~g}\) of \(\mathrm{H}_{2} \mathrm{SO}_{4}\). Eventually, \(28.46 \mathrm{~g}\) of pure \(\mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}\) was isolated. Calculate the percentage yield.

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