Chapter 14: Problem 107
The electronic transition in Na from \(3 p^{1}\) to \(3 s^{1}\) gives rise to a bright yellow-orange emission at \(589.2 \mathrm{nm}\). What is the energy of this transition?
Short Answer
Expert verified
The energy of the transition is approximately \(3.373 \times 10^{-19} \mathrm{J}\).
Step by step solution
01
- Understand the Formula
The energy of a photon can be found using the equation: \[ E = \frac{hc}{\lambda} \]where:\(E\) is the energy,\(h\) is the Planck constant (\(6.626 \times 10^{-34} \mathrm{J \cdot s}\)),\(c\) is the speed of light (\(3.00 \times 10^8 \mathrm{m/s}\)), and\(\lambda\) is the wavelength of the light (in meters).
02
- Convert Wavelength to Meters
The given wavelength is \(589.2 \mathrm{nm}\). Convert it to meters by multiplying by \(10^{-9}\):\[ 589.2 \mathrm{nm} \times 10^{-9} = 5.892 \times 10^{-7} \mathrm{m} \]
03
- Plug Values into the Formula
Insert the values for \(h\), \(c\), and \(\lambda\) into the energy formula:\[ E = \frac{(6.626 \times 10^{-34} \mathrm{J \cdot s}) \times (3.00 \times 10^8 \mathrm{m/s})}{5.892 \times 10^{-7} \mathrm{m}} \]
04
- Calculate the Energy
Perform the calculations to find the energy:\[ E = \frac{1.9878 \times 10^{-25}}{5.892 \times 10^{-7}} \approx 3.373 \times 10^{-19} \mathrm{J} \]
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
photon energy equation
To calculate the energy of a photon, we use a fundamental equation in quantum mechanics. The equation is \( E = \frac{hc}{abla}\), and it links several important constants and variables together, providing a direct way to determine the energy of light from its wavelength.
Here, \( E \) represents the energy of the photon. This is the value we are trying to find.
The term \( h \) stands for Planck’s constant, which we'll discuss more later, and \( c \) is the speed of light.
Lastly, \( abla \) is the wavelength of the photon. The wavelength is essential because it tells us how long the waves of light are, and from this, we can determine its energy.
Plugging these values into the equation involves substituting the constants \( h \) and \( c \), and the specific wavelength \( abla \) of the light we are examining.
Here, \( E \) represents the energy of the photon. This is the value we are trying to find.
The term \( h \) stands for Planck’s constant, which we'll discuss more later, and \( c \) is the speed of light.
Lastly, \( abla \) is the wavelength of the photon. The wavelength is essential because it tells us how long the waves of light are, and from this, we can determine its energy.
Plugging these values into the equation involves substituting the constants \( h \) and \( c \), and the specific wavelength \( abla \) of the light we are examining.
wavelength to meters conversion
Before using the wavelength in our calculations, it must often be converted to meters, the standard unit of length in the International System of Units (SI).
Wavelengths are frequently given in nanometers (nm), especially in the context of visible light. One nanometer is equal to \( 10^{-9} \) meters.
Wavelengths are frequently given in nanometers (nm), especially in the context of visible light. One nanometer is equal to \( 10^{-9} \) meters.
- To convert nanometers to meters, multiply the wavelength by \( 10^{-9} \).
- For example, for our problem, the wavelength \( 589.2 \textrm{ nm} \) becomes \( 589.2 \times 10^{-9} = 5.892 \times 10^{-7} \textrm{m} \).
Planck constant
The Planck constant is a fundamental physical constant used in quantum mechanics. Denoted by \( h \), it has a value of \( 6.626 \times 10^{-34} \) joule-seconds (\textrm{Js}).
It describes the quantization of energy, in simple terms, how the energy of a photon is related to its frequency. In our photon energy equation, Planck's constant helps establish this relationship.
By multiplying Planck’s constant by the speed of light and dividing by the wavelength of light, we are using its significance in the context of energy transmission in quantized form. Remember, \( h \) is a tiny number, indicating that even light waves can carry very small, discrete packets of energy.
It describes the quantization of energy, in simple terms, how the energy of a photon is related to its frequency. In our photon energy equation, Planck's constant helps establish this relationship.
By multiplying Planck’s constant by the speed of light and dividing by the wavelength of light, we are using its significance in the context of energy transmission in quantized form. Remember, \( h \) is a tiny number, indicating that even light waves can carry very small, discrete packets of energy.
speed of light
The speed of light is another essential constant in these calculations. Represented by \( c \), its value is \( 3.00 \times 10^{8} \) meters per second (\textrm{m/s}).
This is the speed at which light travels in a vacuum, and it’s incredibly important in physics and engineering.
When we use the speed of light in our photon energy equation, it helps translate the length of the light wave (the wavelength) into a corresponding energy value.
This is the speed at which light travels in a vacuum, and it’s incredibly important in physics and engineering.
When we use the speed of light in our photon energy equation, it helps translate the length of the light wave (the wavelength) into a corresponding energy value.
- This means light of different wavelengths moves at the same speed but carries different amounts of energy proportional to those wavelengths.
wavelength
The wavelength of light, denoted by the Greek letter lambda \( abla \), is the distance between successive peaks of a wave.
The wavelength determines the color of light and its energy; light with shorter wavelengths (like blue light) carries more energy, while light with longer wavelengths (like red light) carries less energy.
Understanding wavelength is crucial, as it connects directly to how we calculate the energy of photon emissions.
The wavelength determines the color of light and its energy; light with shorter wavelengths (like blue light) carries more energy, while light with longer wavelengths (like red light) carries less energy.
Understanding wavelength is crucial, as it connects directly to how we calculate the energy of photon emissions.
- The unit of measurement for wavelength in our calculations is often meters, even if it's initially given in other units like nanometers.