Chapter 17: Problem 3
If there is no change in concentrations, why is the equilibrium state considered dynamic?
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 17: Problem 3
If there is no change in concentrations, why is the equilibrium state considered dynamic?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeThe following reaction can be used to make \(\mathrm{H}_{2}\) for the synthesis of ammonia from the greenhouse gases carbon dioxide and methane: $$ \mathrm{CH}_{4}(g)+\mathrm{CO}_{2}(g) \rightleftharpoons 2 \mathrm{CO}(g)+2 \mathrm{H}_{2}(g) $$ (a) What is the percent yield of \(\mathrm{H}_{2}\) when an equimolar mixture of \(\mathrm{CH}_{4}\) and \(\mathrm{CO}_{2}\) with a total pressure of 20.0 atm reaches equilibrium at \(1200 . \mathrm{K},\) at which \(K_{\mathrm{p}}=3.548 \times 10^{6} ?\) (b) What is the percent yield of \(\mathrm{H}_{2}\) for this system at \(1300 . \mathrm{K},\) at which \(K_{\mathrm{p}}=2.626 \times 10^{7} ?\) (c) Use the van't Hoff equation to find \(\Delta H_{\mathrm{rnn}}^{\circ}\)
For the following reaction, \(K_{c}=115\) at a particular temperature: $$ \mathrm{H}_{2}(g)+\mathrm{F}_{2}(g) \rightleftharpoons 2 \mathrm{HF}(g) $$ A container initially holds the following concentrations: \(0.050 \mathrm{M}\) \(\mathrm{H}_{2}, 0.050 \mathrm{M} \mathrm{F}_{2},\) and \(0.10 \mathrm{M} \mathrm{HF} .\) When equilibrium is reached, what is the concentration of HF?
Balance each of the following examples of heterogeneous equilibria and write each reaction quotient, \(Q_{c}\) (a) \(\mathrm{NaHCO}_{3}(s) \rightleftharpoons \mathrm{Na}_{2} \mathrm{CO}_{3}(s)+\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g)\) (b) \(\operatorname{SnO}_{2}(s)+\mathrm{H}_{2}(g) \rightleftharpoons \operatorname{Sn}(s)+\mathrm{H}_{2} \mathrm{O}(g)\) (c) \(\mathrm{H}_{2} \mathrm{SO}_{4}(l)+\mathrm{SO}_{3}(g) \rightleftharpoons \mathrm{H}_{2} \mathrm{~S}_{2} \mathrm{O}_{7}(l)\)
Predict the effect of decreasing the temperature on the amount(s) of reactant(s) in the following reactions: (a) \(\mathrm{C}_{2} \mathrm{H}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g) \rightleftharpoons \mathrm{CH}_{3} \mathrm{CHO}(g) \quad \Delta H_{\mathrm{rxn}}^{\circ}=-151 \mathrm{~kJ}\) (b) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}(l)+\mathrm{O}_{2}(g) \rightleftharpoons \mathrm{CH}_{3} \mathrm{CO}_{2} \mathrm{H}(l)+\mathrm{H}_{2} \mathrm{O}(g)\) $$ \Delta H_{\mathrm{rxn}}^{\circ}=-451 \mathrm{~kJ} $$ (c) \(2 \mathrm{C}_{2} \mathrm{H}_{4}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{CH}_{3} \mathrm{CHO}(g)\) (exothermic) (d) \(\mathrm{N}_{2} \mathrm{O}_{4}(g) \rightleftharpoons 2 \mathrm{NO}_{2}(g)\) (endothermic)
Hydrogen sulfide decomposes according to the following reaction, for which \(K_{c}=9.30 \times 10^{-8}\) at \(700^{\circ} \mathrm{C}:\) $$ 2 \mathrm{H}_{2} \mathrm{~S}(g) \rightleftharpoons 2 \mathrm{H}_{2}(g)+\mathrm{S}_{2}(g) $$ If \(0.45 \mathrm{~mol}\) of \(\mathrm{H}_{2} \mathrm{~S}\) is placed in a 3.0 - \(\mathrm{L}\) container, what is the equilibrium concentration of \(\mathrm{H}_{2}(g)\) at \(700^{\circ} \mathrm{C} ?\)
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