Antimony has many uses, for example, in infrared devices and as part of an alloy in lead storage batteries. The element has two naturally occurring isotopes, one with mass 120.904 amu and the other with mass 122.904 amu. (a) Write the \({ }_{Z}^{A} \mathrm{X}\) notation for each isotope. (b) Use the atomic mass of antimony from the periodic table to calculate the natural abundance of each isotope.

Short Answer

Expert verified
Isotopes are \({ }_{51}^{121} Sb\) and \({ }_{51}^{123} Sb\). Natural abundances are 57.2% and 42.8%, respectively.

Step by step solution

01

Identify Atomic Number

The atomic number (Z) of antimony (Sb) can be found in the periodic table. Antimony has an atomic number of 51.
02

- Write Isotope Notation

Using the atomic number (Z = 51) and the given masses, the isotope notation follows the format \({ }_{Z}^{A}X\). For the isotope with mass 120.904 amu, it is \({ }_{51}^{121} Sb\). For the isotope with mass 122.904 amu, it is \({ }_{51}^{123} Sb\).
03

- Gather Necessary Data

The atomic mass of antimony from the periodic table is 121.760 amu, which is a weighted average of its isotopes. Let the natural abundance of the two isotopes be x and (1 - x), where x is the abundance of the isotope with mass 120.904 amu.
04

- Set Up the Equation

To find the natural abundances, set up the following equation based on the weighted average: \[ 120.904x + 122.904(1 - x) = 121.760 \]
05

- Solve for x

First, distribute and simplify the equation: \[ 120.904x + 122.904 - 122.904x = 121.760 \] Combine like terms: \[ -2x + 122.904 = 121.760 \] Subtract 122.904 from both sides: \[ -2x = -1.144 \] Solve for x: \[ x = \frac{1.144}{2} = 0.572 \] Therefore, the natural abundance of the first isotope is 57.2%.
06

- Calculate the Abundance of the Second Isotope

The natural abundance of the second isotope is: \[ 1 - 0.572 = 0.428 \] So, the natural abundance of the second isotope is 42.8%.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Isotope Notation
Isotopes are variations of elements that have the same number of protons but different numbers of neutrons. The isotope notation helps us to identify these variations clearly. It is generally written in the form \({ }_{Z}^{A} \mathrm{X}\). Here,
Z represents the atomic number,
A is the mass number (protons + neutrons),
and X stands for the chemical symbol of the element.
For example, antimony (Sb) has an atomic number (Z) of 51. Two isotopes of antimony can be written using the isotope notation:
For the isotope with a mass of 120.904 amu: \({ }_{51}^{121} \text{Sb}\)
For the isotope with a mass of 122.904 amu: \({ }_{51}^{123} \text{Sb}\).
Using this notation, we can easily identify specific isotopes of any element.
Atomic Number
The atomic number is fundamental to understanding elements and their isotopes. The atomic number (Z) tells us the number of protons in the nucleus of an atom. It is this number that defines the element.
For example, antimony (Sb) has an atomic number of 51, meaning each antimony atom contains 51 protons. The atomic number is always represented as the subscript in the isotope notation \({ }_{Z}^{A} \mathrm{X}\).
It's important to note that while isotopes of an element have the same atomic number (same protons), they have different mass numbers due to the varying number of neutrons.
Natural Abundance
Natural abundance refers to the percentage of a particular isotope naturally found on Earth.
Since most elements exist as a mixture of isotopes, their atomic mass is usually a weighted average of the masses of these isotopes.
Let's consider antimony (Sb), which has two naturally occurring isotopes.
The atomic mass of antimony given in the periodic table is a weighted average, considering the natural abundances and masses of its isotopes.
If we let the natural abundance of the first isotope, \({ }_{51}^{121} \text{Sb}\), be 'x' and the second isotope, \({ }_{51}^{123} \text{Sb}\), be '1 - x', we can set up an equation to find these abundances.
Weighted Average Calculation
Weighted average calculation is crucial for determining the atomic mass of elements with multiple isotopes. Here's a step-by-step approach:
1. Let x be the natural abundance of the first isotope.
2. Therefore, the natural abundance of the second isotope will be (1 - x).
3. Use the atomic mass from the periodic table as the weighted average of the isotopes.
For example, with antimony: \[ 120.904x + 122.904(1 - x) = 121.760 \]
4. Distribute and combine like terms: \[ 120.904x + 122.904 - 122.904x = 121.760 \]
5. Combine and simplify: \[ -2x + 122.904 = 121.760 \]
6. Solve for x: \[ x = \frac{1.144}{2} = 0.572 \]
So, the first isotope has a natural abundance of 57.2%, and the second isotope has an abundance of \[ 1 - 0.572 = 0.428 \] or 42.8%.
Using weighted averages, we can find the natural abundances and understand the contribution of each isotope to the element's atomic mass.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free