During reconstruction of the Statue of Liberty, Teflon spacers were placed between the iron skeleton and the copper plates that cover the statue. What purpose do these spacers serve?

Short Answer

Expert verified
The Teflon spacers prevent galvanic corrosion and accommodate thermal expansion differences.

Step by step solution

01

- Understand the Purpose of Spacers

Spacers are often used in construction to create a gap or buffer between different materials. This helps in preventing direct contact between the materials.
02

- Material Properties

Recognize the materials involved: the iron skeleton and the copper plates. Both iron and copper have different rates of thermal expansion and are prone to corrosion when in direct contact.
03

- Preventing Corrosion

Understand that when two different metals touch, a galvanic reaction may occur, leading to corrosion. Teflon spacers act as an insulator, preventing direct metal-to-metal contact and thus, reducing the risk of corrosion.
04

- Allowing for Thermal Expansion

Different materials expand and contract at different rates when exposed to temperature changes. The spacers provide a buffer allowing each material to expand and contract independently without causing stress or damage.
05

- Conclusion

The Teflon spacers were placed to prevent galvanic corrosion and to accommodate thermal expansion differences between the iron and copper materials, thus preserving the structural integrity and longevity of the Statue of Liberty.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Thermal Expansion
Materials expand and contract with changes in temperature. This is called thermal expansion. Different materials have different rates of thermal expansion. For example, copper and iron expand at different rates when they heat up or cool down.
When these materials are used together, as in the Statue of Liberty, this difference can cause stress. This stress can lead to cracks or other structural issues. Teflon spacers help accommodate these differences. The spacers allow both the copper plates and the iron skeleton to expand and contract independently. This helps in avoiding damage.
By providing a flexible buffer between materials, Teflon spacers absorb the stresses caused by thermal expansion. This is crucial for maintaining the statue's structural integrity over time.
Understanding and addressing thermal expansion is important in many engineering fields. It ensures that structures remain safe and durable as temperatures change.
Explaining Galvanic Reaction
A galvanic reaction occurs when two different metals are in contact in the presence of an electrolyte. In simpler terms, when metals like copper and iron touch and there's moisture, corrosion can happen. This is because electron transfer starts between the metals, leading to one metal corroding more rapidly than the other.
In the case of the Statue of Liberty, iron and copper are the metals in question. When they touch, especially in a marine environment where there's lots of moisture, the risk of galvanic corrosion increases. Over time, this corrosion can weaken the structure. Teflon spacers serve as a barrier between these metals.
By preventing direct metal-to-metal contact, Teflon spacers stop the galvanic reaction from occurring. This keeps the metals from corroding, thus preserving the structural integrity of the statue.
Understanding galvanic reaction and how to prevent it is key for the longevity of metallic structures exposed to different environmental conditions.
Maintaining Structural Integrity
Structural integrity refers to a structure's ability to hold together under a load, without breaking or deforming. For structures like the Statue of Liberty, maintaining structural integrity is critical.
Factors like thermal expansion and galvanic reaction can compromise the integrity of a structure. If not managed well, they can lead to material failure or even collapse. This is where smart engineering solutions, like using Teflon spacers, make a big difference.
Teflon spacers were essential in preserving the statue's structural integrity during its reconstruction. They provided a buffer to manage the stresses from thermal expansion and prevented the corrosion that could have weakened the structure.
Ensuring structural integrity means taking into account all possible stressors and addressing them properly. This helps to extend the lifeline of a structure and keep it safe for years to come.
In summary, Teflon spacers played a vital role in ensuring that the Statue of Liberty remains standing strong and enduring for future generations to admire.

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

In the electrolysis of molten \(\mathrm{BaI}_{2}\) (a) What product forms at the negative electrode? (b) What product forms at the positive electrode?

(a) How do the relative magnitudes of \(Q\) and \(K\) relate to the signs of \(\Delta G\) and \(E_{\text {cell }} ?\) Explain. (b) Can a cell do work when \(Q / K>1\) or \(Q / K<1 ?\) Explain. 21.53 A voltaic cell consists of \(\mathrm{A} / \mathrm{A}^{+}\) and \(\mathrm{B} / \mathrm{B}^{+}\) half-cells, where A and \(B\) are metals and the A electrode is negative. The initial \(\left[\mathrm{A}^{+}\right] /\left[\mathrm{B}^{+}\right]\) is such that \(E_{\text {cell }}>E_{\text {cell }}^{\circ}\) (a) How do \(\left[\mathrm{A}^{+}\right]\) and \(\left[\mathrm{B}^{+}\right]\) change as the cell operates? (b) How does \(E_{\text {cell }}\) change as the cell operates? (c) What is \(\left[\mathrm{A}^{+}\right] /\left[\mathrm{B}^{+}\right]\) when \(E_{\text {cell }}=E_{\text {cell }}^{\circ} ?\) Explain. (d) Is it possible for \(E_{\text {cell }}\) to be less than \(E_{\text {cell }}^{\circ} ?\) Explain.

Use the following half-reactions to write three spontaneous reactions, calculate \(E_{\text {cell }}^{\circ}\) for each reaction, and rank the strengths of the oxidizing and reducing agents: (1) \(2 \mathrm{HClO}(a q)+2 \mathrm{H}^{+}(a q)+2 \mathrm{e}^{-} \longrightarrow \mathrm{Cl}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(I)\) \(E^{\circ}=1.63 \mathrm{~V}\) (2) \(\mathrm{Pt}^{2+}(a q)+2 \mathrm{e}^{-} \longrightarrow \mathrm{Pt}(s) \quad E^{\circ}=1.20 \mathrm{~V}\) (3) \(\mathrm{PbSO}_{4}(s)+2 \mathrm{e}^{-} \longrightarrow \mathrm{Pb}(s)+\mathrm{SO}_{4}^{2-}(a q) \quad E^{\circ}=-0.31 \mathrm{~V}\)

Which statements are true? Correct any that are false. (a) In a voltaic cell, the anode is negative relative to the cathode. (b) Oxidation occurs at the anode of a voltaic or electrolytic cell. (c) Electrons flow into the cathode of an electrolytic cell. (d) In a voltaic cell, the surroundings do work on the system. (e) A metal that plates out of an electrolytic cell appears on the cathode. (f) In an electrochemical cell, the electrolyte provides a solution of mobile electrons.

To examine the effect of ion removal on cell voltage, a chemist constructs two voltaic cells, each with a standard hydrogen electrode in one compartment. One cell also contains a \(\mathrm{Pb} / \mathrm{Pb}^{2+}\) half-cell; the other contains a \(\mathrm{Cu} / \mathrm{Cu}^{2+}\) half-cell. (a) What is \(E^{\circ}\) of each cell at \(298 \mathrm{~K} ?\) (b) Which electrode in each cell is negative? (c) When \(\mathrm{Na}_{2} \mathrm{~S}\) solution is added to the \(\mathrm{Pb}^{2+}\) electrolyte, solid \(\mathrm{PbS}\) forms. What happens to the cell voltage? (d) When sufficient \(\mathrm{Na}_{2} \mathrm{~S}\) is added to the \(\mathrm{Cu}^{2+}\) electrolyte, CuS forms and \(\left[\mathrm{Cu}^{2+}\right]\) drops to \(1 \times 10^{-16} \mathrm{M} .\) Find the cell voltage.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free