Chapter 23: Problem 16
What is the highest oxidation state for (a) Ta; (b) Zr; (c) Mn?
Short Answer
Expert verified
Ta: +5, Zr: +4, Mn: +7
Step by step solution
01
Identify the Element
Locate each element (Ta, Zr, Mn) on the periodic table to understand their positions and general properties.
02
Determine the Group Number
Identify the group number for each element. The group number often indicates the highest possible oxidation state for transition metals, which corresponds to the number of valence electrons available for bonding.
03
Calculate the Oxidation State
For transition metals, the highest oxidation state is typically the same as their group number. But we also consider whether it commonly exhibits such oxidation states.
04
Ta Oxidation State
Tantalum (Ta) is in Group 5. The highest oxidation state is +5.
05
Zr Oxidation State
Zirconium (Zr) is in Group 4. The highest oxidation state is +4.
06
Mn Oxidation State
Manganese (Mn) is in Group 7. The highest oxidation state is +7.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Oxidation State Determination
In chemistry, the oxidation state (or oxidation number) of an element in a compound provides insights into the electron distribution between atoms. Transition metals are known for having multiple oxidation states, which can sometimes make them tricky to evaluate. However, by following a systematic approach, determining oxidation states can become straightforward.
Firstly, locate the element on the periodic table. Knowing its position helps us understand its group and properties. For example, the exercise lists Tantalum (Ta), Zirconium (Zr), and Manganese (Mn).
Next, identify the group number of the element. Transition metals' highest oxidation state often matches their group number because it represents the maximum number of valence electrons available for bonding. In our exercise:
- Tantalum (Ta) is in Group 5, giving it a highest oxidation state of +5.
- Zirconium (Zr) is in Group 4, hence it has a highest oxidation state of +4.
- Manganese (Mn) in Group 7 has a highest oxidation state of +7.
Remember, while the group number provides a starting guideline, some transition metals exhibit common oxidation states that vary from their highest possible state.
Firstly, locate the element on the periodic table. Knowing its position helps us understand its group and properties. For example, the exercise lists Tantalum (Ta), Zirconium (Zr), and Manganese (Mn).
Next, identify the group number of the element. Transition metals' highest oxidation state often matches their group number because it represents the maximum number of valence electrons available for bonding. In our exercise:
- Tantalum (Ta) is in Group 5, giving it a highest oxidation state of +5.
- Zirconium (Zr) is in Group 4, hence it has a highest oxidation state of +4.
- Manganese (Mn) in Group 7 has a highest oxidation state of +7.
Remember, while the group number provides a starting guideline, some transition metals exhibit common oxidation states that vary from their highest possible state.
Transition Metals
Transition metals are elements found in the d-block of the periodic table, which includes groups 3 to 12. They are unique because their d-orbitals are being filled, giving them distinctive properties such as multiple oxidation states, high melting points, and the ability to form colored compounds.
When determining oxidation states, it's important to understand these metals can donate different numbers of electrons, depending on the chemical environment. For instance:
- Tantalum typically has oxidation states of +3 and +5.
- Zirconium usually shows +4 oxidation state.
- Manganese can exhibit a variety of oxidation states, most notably +2, +4, +7.
The variability in oxidation states gives transition metals the ability to form complex compounds and engage in various types of chemical reactions, making them extremely versatile and significant in both biological systems and industrial applications.
When determining oxidation states, it's important to understand these metals can donate different numbers of electrons, depending on the chemical environment. For instance:
- Tantalum typically has oxidation states of +3 and +5.
- Zirconium usually shows +4 oxidation state.
- Manganese can exhibit a variety of oxidation states, most notably +2, +4, +7.
The variability in oxidation states gives transition metals the ability to form complex compounds and engage in various types of chemical reactions, making them extremely versatile and significant in both biological systems and industrial applications.
Periodic Table Groups
The periodic table is divided into groups (columns) and periods (rows). Elements in the same group share similar chemical properties because they have the same number of valence electrons. For transition metals, this commonality drives their behavior and chemical interactions.
Groups are numbered from 1 to 18. For transition metals specifically, their group number can often indicate the maximum oxidation state they can achieve. This simplifies identifying possible oxidation states.
Other important notations include:
- Group 5 elements like Tantalum commonly show an oxidation state of +5.
- Group 4 elements such as Zirconium have an oxidation state of +4.
- Group 7 elements, which include Manganese (Mn), can achieve up to +7.
Understanding the general properties of each group helps in predicting and explaining the chemical behavior of the elements within that group. Thus, analyzing the group numbers provides a framework for determining oxidation states and anticipating the chemistry of transition metals.
Groups are numbered from 1 to 18. For transition metals specifically, their group number can often indicate the maximum oxidation state they can achieve. This simplifies identifying possible oxidation states.
Other important notations include:
- Group 5 elements like Tantalum commonly show an oxidation state of +5.
- Group 4 elements such as Zirconium have an oxidation state of +4.
- Group 7 elements, which include Manganese (Mn), can achieve up to +7.
Understanding the general properties of each group helps in predicting and explaining the chemical behavior of the elements within that group. Thus, analyzing the group numbers provides a framework for determining oxidation states and anticipating the chemistry of transition metals.