Chapter 5: Problem 122
Standard conditions are based on relevant environmental conditions. If normal average surface temperature and pressure on Venus are \(730 . \mathrm{K}\) and \(90 \mathrm{~atm},\) respectively, what is the standard molar volume of an ideal gas on Venus?
Short Answer
Expert verified
0.657 L
Step by step solution
01
Identify the Given Information
The problem states the average surface temperature and pressure on Venus. Temperature: T = 730 KPressure: P = 90 atm
02
Recall the Ideal Gas Law
The Ideal Gas Law is given by the equation: \[ PV = nRT \]Where: P = pressure in atm V = volume in liters n = number of moles (for molar volume, n = 1 mole) R = ideal gas constant (0.0821 L·atm/(mol·K)) T = temperature in Kelvin
03
Solve for Molar Volume (V)
Rearrange the Ideal Gas Law to solve for volume (V):\[ V = \frac{nRT}{P} \]For standard molar volume (n = 1 mole), the equation simplifies to:\[ V = \frac{RT}{P} \]
04
Substitute the Known Values
Insert the known values into the equation:\[ V = \frac{(0.0821 \text{ L·atm/(mol·K)})(730 \text{ K})}{90 \text{ atm}} \]
05
Calculate the Volume
Perform the calculation to find the volume:\[ V = \frac{(0.0821)(730)}{90} \approx \frac{59.133}{90} \approx 0.657 L \]
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ideal Gas Law
The Ideal Gas Law is a central concept in understanding the behavior of gases. It is represented by the equation \[ PV = nRT \] where:
- \(P\) represents pressure
- \(V\) stands for volume
- \(n\) denotes the number of moles of the gas
- \(R\) is the ideal gas constant
- \(T\) signifies temperature.
Standard Molar Volume
Molar volume refers to the volume occupied by one mole of a gas. Under standard conditions on Earth (0°C and 1 atm), one mole of an ideal gas occupies 22.4 liters. However, conditions in real-life scenarios, such as on Venus, differ.
To find the standard molar volume under specific conditions, we use the Ideal Gas Law. For one mole of gas (n = 1), we rearrange the formula to \[ V = \frac{RT}{P} \] This means the volume is determined by the temperature and pressure of the environment.
For example, if the conditions change, like on Venus, the standard molar volume will also change. Always remember to substitute the values correctly, keeping units consistent to avoid errors.
To find the standard molar volume under specific conditions, we use the Ideal Gas Law. For one mole of gas (n = 1), we rearrange the formula to \[ V = \frac{RT}{P} \] This means the volume is determined by the temperature and pressure of the environment.
For example, if the conditions change, like on Venus, the standard molar volume will also change. Always remember to substitute the values correctly, keeping units consistent to avoid errors.
Environmental Conditions on Venus
Venus has extreme environmental conditions compared to Earth. The average surface temperature on Venus is around 730 K (about 457°C), which is significantly hotter than Earth's surface.
Additionally, the pressure on Venus is about 90 atm, much higher than Earth's 1 atm.
These harsh conditions affect how gases behave. In particular, they change the standard molar volume of gases drastically, which demonstrates the importance of accounting for local environmental conditions when using gas laws.
When calculating volumes under such conditions, always use the values specific to the planet or environment you're studying.
Additionally, the pressure on Venus is about 90 atm, much higher than Earth's 1 atm.
These harsh conditions affect how gases behave. In particular, they change the standard molar volume of gases drastically, which demonstrates the importance of accounting for local environmental conditions when using gas laws.
When calculating volumes under such conditions, always use the values specific to the planet or environment you're studying.
Temperature
Temperature is a measure of the average kinetic energy of the particles in a substance. In gas laws like the Ideal Gas Law, temperature needs to be measured in Kelvin (K).
This is because Kelvin is an absolute scale, meaning 0 K (absolute zero) is the theoretical point where particles have minimal kinetic energy. When converting from Celsius to Kelvin, simply add 273.15.
In our Venus example, the temperature is given as 730 K. High temperatures increase the energy of gas particles, which can affect gas volume calculations.
Always ensure your temperature is in Kelvin when working with gas laws to maintain accuracy.
This is because Kelvin is an absolute scale, meaning 0 K (absolute zero) is the theoretical point where particles have minimal kinetic energy. When converting from Celsius to Kelvin, simply add 273.15.
In our Venus example, the temperature is given as 730 K. High temperatures increase the energy of gas particles, which can affect gas volume calculations.
Always ensure your temperature is in Kelvin when working with gas laws to maintain accuracy.
Pressure
Pressure is the force exerted by gas particles colliding with the walls of their container. In the Ideal Gas Law, pressure is expressed in atmospheres (atm).
On Venus, the average surface pressure is around 90 atm, a stark contrast to the 1 atm pressure on Earth's surface.
High pressure on Venus means gas particles are more compressed than they would be at lower pressures. When using the Ideal Gas Law, ensure you use the correct pressure value to avoid inaccurate results.
The formula remains \[ V = \frac{RT}{P} \] but remember, higher pressure results in a smaller volume for the same amount of gas, scenario seen on Venus.
Understanding gas behavior under different pressures is crucial for accurate scientific calculations.
On Venus, the average surface pressure is around 90 atm, a stark contrast to the 1 atm pressure on Earth's surface.
High pressure on Venus means gas particles are more compressed than they would be at lower pressures. When using the Ideal Gas Law, ensure you use the correct pressure value to avoid inaccurate results.
The formula remains \[ V = \frac{RT}{P} \] but remember, higher pressure results in a smaller volume for the same amount of gas, scenario seen on Venus.
Understanding gas behavior under different pressures is crucial for accurate scientific calculations.