150 \(\mathrm{mL}\) of saturated \(\mathrm{SrF}_{2}\) solution is present in a 250 \(\mathrm{mL}\) beaker at room temperature. The molar solubility of \(\mathrm{SrF}_{2}\) at 298 \(\mathrm{K}\) is \(1.0 \times 10^{-3} \mathrm{M}\) . How could the concentration of \(\mathrm{Sr}^{2+}\) ions in solution be decreased? (A) Adding some \(\operatorname{NaF}(s)\) to the beaker (B) Adding some \(\operatorname{Sr}\left(\mathrm{NO}_{3}\right)_{2}(s)\) to the beaker (C) By heating the solution in the beaker (D) By adding a small amount of water to the beaker, but not dissolving all the solid

Short Answer

Expert verified
The concentration of \(Sr^{2+}\) ions in solution can be decreased by adding some \(NaF(s)\) to the beaker.

Step by step solution

01

Identify the Equilibrium Shift

First, it is crucial to understand that by adding a reactive component to this system or changing its conditions, the system will adapt to maintain the solubility equilibrium. This is aligned with Le Chatelier's principle.
02

Examine Each Option

Now, evaluate each option individually to see how it would impact the system. (A) Adding some \(NaF(s)\) would increase the concentration of \(F^{-}\) ions in the solution. This in turn would push the equation to the left, reducing the concentration of \(Sr^{2+}\). (B) Adding \(Sr(NO_{3})_{2}(s)\) to the beaker would increase the concentration of \(Sr^{2+}\), shifting the equilibrium to the left but increasing the \(Sr^{2+}\) ion concentration. (C) Heating the solution would typically favor the endothermic direction. Without information regarding the enthalpy change (\(ΔH\)), we cannot tell which direction would be favored by heat. (D) Adding water would increase the volume of solution, causing dilution. The concentration of ions would initially decrease, but the system would reestablish equilibrium by dissolving more \(SrF_{2}\), potentially leading to no real change in \(Sr^{2+}\) concentration.
03

Determine the Suitable Option

Based on the analysis, option (A) adding \(NaF(s)\) would effectively decrease the concentration of \(Sr^{2+}\) ions in solution without reestablishing equilibrium.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

How many liters of distilled water must be added to 1 liter of an aqueous solution of HCl with a pH of 1 to create a solution with a pH of 2? (A) 0.1 L (B) 0.9 L (C) 2 L (D) 9 L

A laboratory technician wishes to create a buffered solution with a pH of 5. Which of the following acids would be the best choice for the buffer? (A) \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4} \quad K_{a}=5.9 \times 10^{-2}\) (B) \(\mathrm{H}_{3} \mathrm{AsO}_{4} \quad K_{a}=5.6 \times 10^{-3}\) (C) \(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{H}_{3} \mathrm{O}_{2} \quad K_{a}=1.8 \times 10^{-5}\) (D) \(\mathrm{HOCl}\) \(\quad K_{a}=3.0 \times 10^{-8}\)

Questions 45-48 refer to the following. Inside a calorimeter, 100.0 \(\mathrm{mL}\) of 1.0 \(\mathrm{M}\) hydrocyanic acid (HCN), a weak acid, and 100.0 \(\mathrm{mL}\) of 0.50 \(\mathrm{M}\) sodium hydroxide are mixed. The temperature of the mixture rises from \(21.5^{\circ} \mathrm{C}\) to \(28.5^{\circ} \mathrm{C}\) . The specific heat of the mixture is approximately \(4.2 \mathrm{J} / \mathrm{g}^{\circ} \mathrm{C},\) and the density is identical to that of water. As \(\Delta T\) increases, what happens to the equilibrium constant and why? (A) The equilibrium constant increases because more products are created. (B) The equilibrium constant increases because the rate of the forward reaction increases. (C) The equilibrium constant decreases because the equilibrium shifts to the left. (D) The value for the equilibrium constant is unaffected by temperature and will not change.

Which of the following substances has an asymmetrical molecular structure? (A) \(\mathrm{SF}_{4}\) (B) \(\mathrm{PCl}_{5}\) (C) \(\mathrm{BF}_{3}\) (D) \(\mathrm{CO}_{2}\)

Questions 32-36 refer to the following. Two half-cells are set up as follows: Half-Cell A: Strip of \(\mathrm{Cu}(s)\) in \(\mathrm{CuNO}_{3}(a q)\) Half-Cell B: Strip of \(\mathrm{Zn}(s)\) in \(\mathrm{Zn}\left(\mathrm{NO}_{3}\right)_{2}\) (aq) When the cells are connected according to the diagram below, the following reaction occurs: GRAPH CAN'T COPY $$2 \mathrm{Cu}^{+}(a q)+\mathrm{Zn}(s) \rightarrow 2 \mathrm{Cu}(s)+\mathrm{Zn}^{2+}(a q) E^{\circ}=+1.28 \mathrm{V}$$ If the \(\mathrm{Cu}^{+}+e^{-} \rightarrow \mathrm{Cu}(s)\) half-reaction has a standard reduction potential of \(+0.52 \mathrm{V},\) what is the standard reduction potential for the \(\mathrm{Zn}^{2+}+2 e^{-} \rightarrow \mathrm{Zn}(s)\) half-reaction? (A) \(+0.76 \mathrm{V}\) (B) \(-0.76 \mathrm{V}\) (C) \(+0.24 \mathrm{V}\) (D) \(-0.24 \mathrm{V}\)

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free