What is the general relationship between temperature and entropy for diatomic gases? (A) They are completely independent of each other; temperature has no effect on entropy. (B) There is a direct relationship, because at higher temperatures there is an increase in energy dispersal. (C) There is an inverse relationship, because at higher temperatures substances are more likely to be in a gaseous state. (D) It depends on the specific gas and the strength of the intermolecular forces between individual molecules.

Short Answer

Expert verified
The general relationship between temperature and entropy for diatomic gases is a direct one, because at higher temperatures there is an increase in energy dispersal, and hence more possible states or randomness (Option B).

Step by step solution

01

Understanding the concept of entropy

Entropy is a measure of the randomness or disorder of a system. The second law of thermodynamics states that in a closed system, entropy will always increase. This is also known as the law of increasing entropy. In other words, nature tends towards maximum entropy.
02

Understanding the effect of temperature on entropy

The higher the temperature, the more kinetic energy a system has. This increased energy allows for an increased number of possible states or arrangements the system can have, thereby increasing the randomness or entropy.
03

Evaluating the provided options

Given the understanding of entropy and temperature, it is now possible to assess the provided options. Option A suggests that temperature and entropy are completely independent of each other, which is definitively incorrect. The idea that there is an inverse relationship between temperature and entropy, as suggested by Option C, is also incorrect. Entropy typically increases with temperature, not decreases. Option D suggests that the relationship between temperature and entropy depends on the specific gas and the strength of the intermolecular forces. While the strength of intermolecular forces can affect the amount of entropy change, it does not change the general relationship that as temperatures increase, so does entropy.
04

Making a conclusion

Based on the understanding of entropy and temperature and the evaluation of each option, it can be concluded that Option B is the most accurate. This option states that at higher temperatures there is an increase in energy dispersal, which matches the understanding of temperature's effect on entropy.

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