How many electrons occur in the valence level of Group \(3 \mathrm{~A}(13)\) and \(3 \mathrm{~B}(3)\) elements? Why are they different?

Short Answer

Expert verified
Both Group 3A(13) and Group 3B(3) elements have three valence electrons, but they differ because in Group 3B, two are in the s orbital and one is in the d orbital, while in Group 3A the electrons are in the p orbital.

Step by step solution

01

Identify the Electron Configuration of Group 3A(13) Elements

Group 3A(13) elements have three electrons in the outermost shell. This group includes elements like aluminum (Al), gallium (Ga), and indium (In). The valence electron configuration for these elements typically ends in p1, with the preceding s orbital being filled (s2).
02

Identify the Electron Configuration of Group 3B(3) Elements

Group 3B(3) elements, also known as the scandium group, include scandium (Sc) and yttrium (Y). These have two electrons in the outermost s orbital and one electron in the d orbital. Consequently, they also have three electrons in the outer shell. However, the energy level of the d orbital electron is different from the p orbital electron in Group 3A(13) elements.
03

Explain the Difference in Electron Configuration

The difference in valence electrons is due to the different orbitals in which these electrons are located. For Group 3A(13), the valence electrons are in the p orbital, while for Group 3B(3), two are in the s orbital and the third is in the d orbital. Group 3B elements also have additional inner d or f electrons that are not valence electrons.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Electron Configuration
Understanding the electron configuration of an atom is essential for determining its chemical properties. The electron configuration tells us how the electrons are distributed among the various orbitals around the nucleus. Electrons fill subatomic orbitals in a defined order, occupying the lowest energy levels before the higher ones.

For example, the electron configuration of aluminum, a Group 3A(13) element, begins with electrons filling the lower energy s and p orbitals before adding an electron to the p orbital in its outermost shell. Its configuration, expressed using shorthand notation, is [Ne]3s23p1, indicating a filled 3s orbital and a single electron in the 3p orbital. Group 3B(3) elements, on the other hand, also include electrons in d orbitals, which leads to a difference in the chemical behavior of these elements despite both groups having three valence electrons.
Periodic Table Group
The periodic table group is a way of categorizing elements based on shared properties and configurations of their valence electrons. Elements in the same group typically have similar valence electron configurations, resulting in similar chemical behaviors.

For instance, Group 3A(13) elements have valence electrons in the 'p' block, specifically the p orbital, which gives them certain predictable properties. In contrast, Group 3B(3) elements have their valence electrons in both the 's' and 'd' orbitals, influencing their characteristic reactions and bonding with other elements. Understanding the groupings on the periodic table can help predict how an element will interact chemically, which is crucial for fields such as chemistry and materials science.
S and P Orbitals
Atomic orbitals are regions around the nucleus where electrons are likely to be found. The 's' and 'p' orbitals are two types of orbitals that play a significant role in chemical bonding and electron configuration.

Traits of S Orbitals:

  • S orbitals are spherical in shape.
  • Each energy level from 1s upwards has one s orbital.
  • An s orbital can hold a maximum of two electrons.

Traits of P Orbitals:

  • P orbitals are dumbbell-shaped.
  • Starting at the second energy level, each level has three p orbitals, designated px, py, and pz.
  • Each p orbital can hold a maximum of two electrons, allowing for six electrons in total.
Valence electrons in the s and p orbitals determine many of the reactive properties of elements. For Group 3A(13) elements, the valence electron configuration typically ends in 'p1', indicating one electron in the p orbital. The 's' orbital, on a lower energy level, is filled with two electrons. This configuration has a profound effect on the chemical properties and reactivity of these elements.

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Most popular questions from this chapter

Element 87 is in Group \(1 \mathrm{~A}(1)\), Period 7. In how many principal energy levels are electrons located? Describe its outermost energy level.

For each of the electron configurations given, write the corresponding orbital diagrams. (a) \(\mathrm{F} \quad 1 s^{2} 2 s^{2} 2 p^{5}\) (b) \(\mathrm{S} \quad 1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{4}\) (c) Co \(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} 3 d^{7}\) (d) \(\mathrm{Kr} \quad 1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} 3 d^{10} 4 p^{6}\) (e) Ru \(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{2} 3 d^{10} 4 p^{6} 5 s^{2} 4 d^{6}\)

If a \(p\) sublevel has five electrons, which orbitals will they occupy? Draw the sublevel using arrows to represent electrons and show spin based on the direction of the arrow.

A dog is suspected of attacking a runner in the park. This runner was wearing a pearlescent lip gloss containing bismuth hypochlorite, a compound often used in cosmetics to give this pearlescent effect. Upon analyzing a residue on the dog's fur, this compound is detected giving additional support to the victim's claim. Write the complete and shorthand electron configurations for bismuth.

Chromium is a lustrous silver-colored metal that has been used to prevent corrosion for centuries. Bronze swords and other weapons discovered in burial pits from the Qin Dynasty were coated with chromium and had not corroded at all since their entombing. Today many items are coated with a layer of chromium as a decorative and protective covering. (a) Sometimes the actual electron configurations of the elements differ from those predicted by the periodic table. The experimentally determined electron configuration for chromium is \(1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 4 s^{1} 3 d^{5}\). Is this the electron configuration you would predict based on the periodic table? If not, what is the configuration predicted by the periodic table for chromium? (b) Chromium has a density of \(7.19 \mathrm{~g} / \mathrm{cm}^{3}\). How many atoms of chromium are contained in a \(5.00-\mathrm{cm}^{3}\) sample of chromium? (c) If the radius of a chromium atom is \(1.40 \times 10^{-8} \mathrm{~cm}\), what is the volume \(\left(V=\frac{4}{3} \pi r^{3}\right)\) of a single chromium atom? (d) How many chromium atoms occupy a volume of \(5.00 \mathrm{~cm}^{3}\) ?

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