Chapter 12: Problem 43
At what Kelvin temperature will \(25.2 \mathrm{~mol}\) of Xe occupy a volume of \(645 \mathrm{~L}\) at a pressure of 732 torr?
Short Answer
Expert verified
300.4 K
Step by step solution
01
- Identify the given values
Given values are: - Number of moles, n = 25.2 mol - Volume, V = 645 L - Pressure, P = 732 torr
02
- Convert pressure to atmospheres
Convert the given pressure from torr to atmospheres using the conversion factor (1 atm = 760 torr): \( P = \frac{732 \, \text{torr}}{760 \, \text{torr/atm}} = 0.963 \, \text{atm} \)
03
- Use the Ideal Gas Law
The Ideal Gas Law is given by \( PV = nRT \). In this case, we are solving for the temperature, T. Rearrange the formula to solve for T: \( T = \frac{PV}{nR} \)
04
- Insert the values and solve for T
Insert the given values into the rearranged Ideal Gas Law equation: \[ n = 25.2 \, \text{mol} \] \[ V = 645 \, \text{L} \] \[ P = 0.963 \, \text{atm} \] \[ R = 0.0821 \, \text{L} \, \text{atm} \, \text{K}^{-1} \, \text{mol}^{-1} \] \[ T = \frac{(0.963 \, \text{atm}) (645 \, \text{L})}{(25.2 \, \text{mol}) (0.0821 \, \text{L} \, \text{atm} \, \text{K}^{-1} \, \text{mol}^{-1})} \] \[ T = \frac{621.135}{2.06772} \, \text{K} \] \[ T \approx 300.4 \, \text{K} \]
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Kelvin temperature calculation
In chemistry, temperature is often measured in Kelvin instead of Celsius or Fahrenheit. The Kelvin scale starts at absolute zero. When doing calculations with the Ideal Gas Law, it's essential to use Kelvin. This scale helps make the math simpler and more accurate.
To convert Celsius to Kelvin, simply add 273.15 to the Celsius temperature. For example, if a temperature is 25°C, it would be 298.15 K when converted. Similarly, if it were -10°C, it would be 263.15 K in Kelvin.
Understanding and accurately using the Kelvin scale is crucial, especially in gas law calculations where temperature must be in absolute units.
To convert Celsius to Kelvin, simply add 273.15 to the Celsius temperature. For example, if a temperature is 25°C, it would be 298.15 K when converted. Similarly, if it were -10°C, it would be 263.15 K in Kelvin.
Understanding and accurately using the Kelvin scale is crucial, especially in gas law calculations where temperature must be in absolute units.
pressure conversion
Pressure in gas law problems is often given in various units like torr, atmospheres (atm), or Pascals (Pa). To make calculations consistent and correct, it is vital to convert these pressures into a common unit, usually atmospheres.
For example, in our problem, the pressure is given as 732 torr. To convert to atmospheres, use the conversion factor: 1 atm = 760 torr. Therefore, \( P = \frac{732 \text{ torr}}{760 \text{ torr/atm}} = 0.963 \text{ atm} \).
This conversion ensures you can accurately use the Ideal Gas Law, which typically uses atmospheres for pressure.
For example, in our problem, the pressure is given as 732 torr. To convert to atmospheres, use the conversion factor: 1 atm = 760 torr. Therefore, \( P = \frac{732 \text{ torr}}{760 \text{ torr/atm}} = 0.963 \text{ atm} \).
This conversion ensures you can accurately use the Ideal Gas Law, which typically uses atmospheres for pressure.
gas moles and volume relationship
The amount of gas (in moles) and its volume have a direct relationship, as described by the Ideal Gas Law (PV = nRT). The term 'mole' refers to a specific quantity of molecules. One mole contains Avogadro's number of molecules (approximately 6.022 x 10^23).
In our exercise, we're given that 25.2 moles (n) of Xe gas occupies a volume of 645 L. This relationship is crucial because we use this value of moles and volume along with the other variables in the Ideal Gas Law equation.
Remember: More moles of gas will generally result in a higher volume if the pressure and temperature are kept constant, highlighting the directly proportional relationship.
In our exercise, we're given that 25.2 moles (n) of Xe gas occupies a volume of 645 L. This relationship is crucial because we use this value of moles and volume along with the other variables in the Ideal Gas Law equation.
Remember: More moles of gas will generally result in a higher volume if the pressure and temperature are kept constant, highlighting the directly proportional relationship.
Ideal Gas Law equation usage
The Ideal Gas Law, represented by the equation \( PV = nRT \), is fundamental for understanding the behavior of gases. This equation combines the physical properties of pressure (P), volume (V), amount of gas in moles (n), and temperature (T) using the Ideal Gas Constant (R).
To find an unknown, rearrange the equation. In our example, we're solving for temperature (T). So, rearrange to \( T = \frac{PV}{nR} \).
Insert the known values: \( P = 0.963 \text{ atm}, V = 645 \text{ L}, n = 25.2 \text{ mol}, R = 0.0821 \text{ L atm K}^{-1} \text{ mol}^{-1} \). This results in \( T = \frac{(0.963 \text{ atm}) (645 \text{ L})}{(25.2 \text{ mol}) (0.0821 \text{ L atm K}^{-1} \text{ mol}^{-1})} = 300.4 \text{ K} \).
Using the Ideal Gas Law helps predict how changing one variable affects the others, making it an essential tool in chemistry.
To find an unknown, rearrange the equation. In our example, we're solving for temperature (T). So, rearrange to \( T = \frac{PV}{nR} \).
Insert the known values: \( P = 0.963 \text{ atm}, V = 645 \text{ L}, n = 25.2 \text{ mol}, R = 0.0821 \text{ L atm K}^{-1} \text{ mol}^{-1} \). This results in \( T = \frac{(0.963 \text{ atm}) (645 \text{ L})}{(25.2 \text{ mol}) (0.0821 \text{ L atm K}^{-1} \text{ mol}^{-1})} = 300.4 \text{ K} \).
Using the Ideal Gas Law helps predict how changing one variable affects the others, making it an essential tool in chemistry.