The heat of fusion of a substance is given in units of \(\mathrm{J} / \mathrm{g}\). The specific heat of a substance is given in units of \(\mathrm{J} / \mathrm{g}{ }^{\circ} \mathrm{C}\). Why is a temperature factor not needed in the units for heat of fusion?

Short Answer

Expert verified
Heat of fusion does not have a temperature factor because it does not change the temperature of the substance, only its state.

Step by step solution

01

Define Heat of Fusion

Heat of fusion is the amount of energy needed to change a substance from solid to liquid at its melting point without changing its temperature. It is measured in \(\text{Joules per gram} (\mathrm{J} / \mathrm{g})\).
02

Define Specific Heat

Specific heat is the amount of energy needed to raise the temperature of 1 gram of a substance by 1 degree Celsius. It is measured in \(\text{Joules per gram per degree Celsius} (\mathrm{J} / \mathrm{g}{ }^{\circ}\mathrm{C})\).
03

Compare Units and Temperature Dependency

The units for specific heat contain a temperature factor (\(^{\circ}\mathrm{C}\)) because energy input changes the temperature of the substance. For heat of fusion, no temperature factor is needed because the energy is used to change the state of the substance at its melting point, not to change its temperature.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

specific heat
Specific heat is a fundamental concept in thermodynamics. It refers to the amount of energy required to raise the temperature of 1 gram of a substance by 1 degree Celsius. You measure it in units of Joules per gram per degree Celsius \((\mathrm{J} / \mathrm{g}{ }^{\circ}\mathrm{C})\). Whether you are heating water to make tea or warming a metal object, you are dealing with specific heat.

The key takeaway here is that different materials require different amounts of energy to change their temperatures. For example, water has a high specific heat, meaning it absorbs a lot of heat before its temperature changes noticeably. On the other hand, metals typically have lower specific heats and require less energy for a temperature increase.

Specific heat depends on several factors like the type of material and its current state (solid, liquid, or gas). By understanding specific heat, you can gain insight into how different substances react to thermal energy changes.
energy transformation
Energy transformation is a process where energy changes from one form to another. In the context of heat of fusion and specific heat, we focus on thermal energy.

Let's start with heat of fusion. This type of energy transformation happens when a solid turns into a liquid. For instance, when ice melts into water, it absorbs energy from its surroundings, known as the heat of fusion. This energy goes into changing the state of the substance rather than its temperature.

On the other hand, for the specific heat process, the energy transformation results in a temperature rise of the substance. When you heat up water on a stove, the energy from the burner transforms into thermal energy, which in turn increases the water's temperature.

These two forms of energy transformation have distinct applications and consequences. Knowing them helps you understand various physical and chemical phenomena more comprehensively.
melting point
The melting point is the specific temperature at which a solid turns into a liquid. This is a crucial temperature point for any substance. At the melting point, the substance absorbs energy without increasing its temperature. Instead, this absorbed energy, known as the heat of fusion, is utilized to alter the substance's state.

Consider ice melting into water at 0 degrees Celsius. Despite absorbing heat, the temperature remains constant until all the ice has melted. The energy added doesn't increase the temperature; it only facilitates the phase transition.

Melting points vary between substances due to differences in molecular structures and bonding. For example, table salt has a much higher melting point compared to ice. Knowing the melting point is essential for practical applications like material processing and cooking.
temperature dependency
Temperature dependency is a concept that illustrates how different properties of materials change with temperature. Specific heat is a clear example. As the temperature of a substance rises, it requires more energy per gram to continue increasing its temperature linearly. This is why the unit includes a temperature factor \((\mathrm{J} / \mathrm{g}{ }^{\circ}\mathrm{C})\).

In contrast, heat of fusion is not temperature-dependent in the same way. The energy required to change a substance from solid to liquid remains constant at the melting point, regardless of additional temperature changes. This is why there’s no temperature factor in its unit \((\mathrm{J} / \mathrm{g})\).

Understanding temperature dependency is essential for applications in science and engineering. It helps in designing systems that involve heating or cooling and in predicting how materials will respond under different thermal conditions.

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Most popular questions from this chapter

You leave the house wearing a cotton T-shirt and are surprised by a sudden rainstorm. You notice that the water soaks into the T-shirt whereas it just beads up on your raincoat. In this example, are the adhesive forces or cohesive forces stronger between water and your T-shirt? Between water and your raincoat? Explain.

Suppose 100 . g of ice at \(0^{\circ} \mathrm{C}\) are added to 300 . \(\mathrm{g}\) of water at \(25^{\circ} \mathrm{C}\). Is this sufficient ice to lower the temperature of the system to \(0^{\circ} \mathrm{C}\) and still have ice remaining? Show evidence for your answer.

A hydrated iron chloride compound was found to contain \(20.66 \% \mathrm{Fe}, 39.35 \% \mathrm{Cl}\), and \(39.99 \%\) water. Determine the empirical formula of this hydrated compound.

You buy a box of borax \(\left(\mathrm{Na}_{2} \mathrm{~B}_{4} \mathrm{O}_{7} \cdot 10 \mathrm{H}_{2} \mathrm{O}\right)\) from the corner market in Phoenix, Arizona, in the middle of the summer. You open up the box and pour the borax into a weighed beaker. After all, you do want to be sure that you were not cheated by the manufacturer. You are distracted from your task and do not get back to weigh the filled beaker for several days. Upon weighing the beaker, you get the following data from the \(5.0-\mathrm{lb}\) box of borax. Empty beaker \(\quad 492.5 \mathrm{~g}\) Filled beaker \(\quad 2467.4 \mathrm{~g}\) Were you cheated by the manufacturer? Why or why not?

Ether has a higher vapor pressure than water. Which of these two liquids has stronger intermolecular forces? Which liquid would you expect to have the higher boiling point?

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