Calculate the grams of solute in each of the following solutions: (a) \(1.20 \mathrm{~L}\) of \(18 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) (b) \(27.5 \mathrm{~mL}\) of \(1.50 \mathrm{M} \mathrm{} \mathrm{KMnO}_{4}\) (c) \(120 \mathrm{~mL}\) of \(0.025 \mathrm{M} \mathrm{Fe}_{2}\left(\mathrm{SO}_{4}\right)_{3}\)

Short Answer

Expert verified
The grams of solute in each solution are: (a) 2118.528 g of H2SO4, (b) 6.53 g of KMnO4, (c) 1.20 g of Fe2(SO4)3.

Step by step solution

01

- Calculate mass of solute for solution (a)

First, calculate moles of solute using molarity (M) formula: Moles = Molarity * Volume. For H2SO4: Moles of H2SO4 = 18 M * 1.20 L = 21.6 moles.
02

- Convert moles to grams for solution (a)

Next, convert moles of H2SO4 to grams using its molar mass. Molar mass of H2SO4 = 2(1.01) + 32.07 + 4(16.00) ≈ 98.08 g/mol. Mass of H2SO4 = 21.6 moles * 98.08 g/mol ≈ 2118.528 g.
03

- Calculate mass of solute for solution (b)

First, convert the volume from mL to L: 27.5 mL = 0.0275 L. Calculate moles of KMnO4 using molarity: Moles of KMnO4 = 1.50 M * 0.0275 L = 0.04125 moles.
04

- Convert moles to grams for solution (b)

Convert moles of KMnO4 to grams using its molar mass. Molar mass of KMnO4 = 39.10 + 54.94 + 4(16.00) ≈ 158.04 g/mol. Mass of KMnO4 = 0.04125 moles * 158.04 g/mol ≈ 6.53 g.
05

- Calculate mass of solute for solution (c)

First, convert the volume from mL to L: 120 mL = 0.120 L. Calculate moles of Fe2(SO4)3 using molarity: Moles of Fe2(SO4)3 = 0.025 M * 0.120 L = 0.003 moles.
06

- Convert moles to grams for solution (c)

Convert moles of Fe2(SO4)3 to grams using its molar mass. Molar mass of Fe2(SO4)3 = 2(55.85) + 3(32.07 + 4(16.00)) ≈ 399.88 g/mol. Mass of Fe2(SO4)3 = 0.003 moles * 399.88 g/mol ≈ 1.20 g.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Molar Mass
Molar mass is a fundamental concept in chemistry that refers to the mass of one mole of a substance, usually expressed in grams per mole (g/mol). It is calculated by adding the atomic masses of all the atoms in a molecule. For example, water (H2O) has a molar mass of approximately 18 g/mol because it consists of two hydrogen atoms (each with an atomic mass of approximately 1 g/mol) and one oxygen atom (approximately 16 g/mol).

Understanding molar mass is crucial for converting between the mass of a substance and the amount of substance in moles. It's the bridge between the microscopic world of atoms and molecules and the macroscopic world we measure in labs.
Molarity to Grams Conversion
Molarity to grams conversion is a technique used to find the mass of a solute in a given volume of solution. Molarity, defined as the number of moles of solute per liter of solution (mol/L), tells us the concentration of a substance in a solution. To perform this conversion, you first need to find the number of moles of solute using the equation: \
\( \text{Moles} = \text{Molarity} \times \text{Volume} \)

Once the number of moles is found, you can convert it to grams by multiplying it by the substance's molar mass. This process is illustrated in the textbook exercise, where the molarity and volumes of different solutions were given, and the task was to find the mass of the dissolved substances. By mastering this conversion, students learn to transition seamlessly from conceptual to practical applications of molarity in the laboratory.
The Role of Stoichiometry in Molarity Calculations
Stoichiometry is a section of chemistry that involves calculating the relative quantities of reactants and products in chemical reactions. It is based on the conservation of mass and the concept of the mole. In molarity calculations, stoichiometry comes into play when you need to know how different substances in a reaction relate to one another quantitatively.

For instance, if a chemical equation indicates that two moles of hydrogen react with one mole of oxygen to form water, stoichiometry allows us to calculate the amount of oxygen needed to react with a certain volume of hydrogen at a known molarity or the volume of water produced from this reaction. Learning stoichiometry provides students with the skills to predict the outcomes of chemical reactions, which is essential for both academic and real-world lab settings.

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Most popular questions from this chapter

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Use the equation to calculate the following: \(2 \mathrm{NaOH}(a q)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{Na}_{2} \mathrm{SO}_{4}(a q)+2 \mathrm{H}_{2} \mathrm{O}(l)\) (a) the moles of \(\mathrm{Na}_{2} \mathrm{SO}_{4}\) produced from \(3.6 \mathrm{~mol} \mathrm{H} \mathrm{H}_{2} \mathrm{SO}_{4}\) (b) the moles of \(\mathrm{H}_{2} \mathrm{O}\) produced from \(0.025 \mathrm{~mol} \mathrm{NaOH}\) (c) the moles of \(\mathrm{NaOH}\) required to react with \(2.50 \mathrm{~L}\) of \(0.125 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) (d) the grams of \(\mathrm{Na}_{2} \mathrm{SO}_{4}\) that can be obtained from \(25 \mathrm{~mL}\) of \(0.050 \mathrm{M} \mathrm{NaOH}\) (e) the volume of \(0.250 \mathrm{MH}_{2} \mathrm{SO}_{4}\) needed to react with \(25.5 \mathrm{~mL}\) of \(0.750 \mathrm{M} \mathrm{NaOH}\) (f) the molarity \((M)\) of the \(\mathrm{NaOH}\) solution when \(48.20 \mathrm{~mL}\) react with \(35.72 \mathrm{~mL}\) of \(0.125 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\)

A bleaching solution requires \(5.23\) g of sodium hypochlorite. How many grams of a \(21.5 \%\) by mass solution of sodium hypochorite should be used?

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