A sugar syrup solution contains \(15.0 \%\) sugar, \(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\), by mass and has a density of \(1.06 \mathrm{~g} / \mathrm{mL}\). (a) How many grams of sugar are in \(1.0 \mathrm{~L}\) of this syrup? (b) What is the molarity of this solution? (c) What is the molality of this solution?

Short Answer

Expert verified
159 g of sugar in 1 L of syrup. Molarity is 0.464 M. Molality is 0.515 m.

Step by step solution

01

- Calculate mass of the syrup in 1 liter

The density of the syrup is given as \(1.06 \, \text{g/mL}\). Since there are 1000 mL in 1 L, the mass of the syrup in 1 L is: \[ \text{Mass} = 1.06 \, \frac{\text{g}}{\text{mL}} \times 1000 \, \text{mL} = 1060 \, \text{g}. \]
02

- Calculate grams of sugar in 1 liter of syrup

The syrup contains 15.0% sugar by mass. Therefore, the mass of sugar in 1060 g of syrup is: \[ \text{Mass of sugar} = 0.15 \times 1060 \, \text{g} = 159 \, \text{g}. \]
03

- Convert grams of sugar to moles

The molar mass of sugar (\(\mathrm{C}_{12}\mathrm{H}_{22}\mathrm{O}_{11}\)) is calculated as follows: \[ \begin{align*} \text{Molar mass of } \mathrm{C}_{12}\mathrm{H}_{22}\mathrm{O}_{11} &= (12 \times 12.01) + (22 \times 1.01) + (11 \times 16.00) \ &= 144.12 + 22.22 + 176.00 \ &= 342.34 \, \text{g/mol} \end{align*} \] Therefore, the moles of sugar are calculated by: \[ \text{Moles of sugar} = \frac{159 \, \text{g}}{342.34 \, \text{g/mol}} \approx 0.464 \, \text{mol}. \]
04

- Calculate molarity of the solution

Molarity (\(M\)) is the number of moles of solute per liter of solution. Here, we have 0.464 moles of sugar in 1 liter of solution: \[ M = \frac{0.464 \, \text{mol}}{1.0 \, \text{L}} = 0.464 \, \text{M}. \]
05

- Calculate the mass of water in the solution

The mass of the syrup is 1060 g, and the mass of sugar in it is 159 g. Therefore, the mass of water in the solution is: \[ \text{Mass of water} = 1060 \, \text{g} - 159 \, \text{g} = 901 \, \text{g} \]
06

- Convert mass of water to kilograms

To find molality, we need the mass of water in kilograms: \[ \text{Mass of water in kg} = \frac{901 \, \text{g}}{1000} = 0.901 \, \text{kg} \]
07

- Calculate molality of the solution

Molality (\(m\)) is the number of moles of solute per kilogram of solvent. Therefore: \[ m = \frac{0.464 \, \text{mol}}{0.901 \, \text{kg}} \approx 0.515 \, \text{m}. \]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

molarity
Molarity is a measure of the concentration of a solute in a solution. It is defined as the number of moles of solute per liter of solution. This is represented by the symbol M. When we say a solution is '1 M,' it means there is 1 mole of solute in every liter of solution.

For example, in the given problem, we calculated the number of moles of sugar (solute) in 1 liter of sugar syrup (solution) as 0.464 moles. Therefore, the molarity of the sugar syrup is 0.464 M. This helps us determine the concentration of the sugar in the solution in a straightforward manner.

To recap, molarity (M) can be calculated using the formula: \( M = \frac{\text{moles of solute}}{\text{liters of solution}} \). This concept is fundamental in understanding the concentration of solutions in chemistry.
molality
While molarity measures the concentration based on the volume of the solution, molality focuses on the mass of the solvent. Molality (m) is defined as the number of moles of solute per kilogram of solvent.

In the given problem, after determining the mass of water (solvent) in the syrup as 901 g (or 0.901 kg), we calculated the molality of the solution. With 0.464 moles of sugar (solute) and 0.901 kg of water (solvent), the molality is: \( m = \frac{0.464 \, \text{mol}}{0.901 \, \text{kg}} \approx 0.515 \, \text{m} \). This measure helps when the temperature and pressure impact the volume but not the mass, making it useful for comparing concentrations under different conditions.
density
Density is a physical property defined as mass per unit volume. It can be represented by the formula: \( \text{Density} = \frac{\text{mass}}{\text{volume}} \).

In the problem, the density of the sugar syrup is given as 1.06 g/mL. Using the density, we can calculate the mass of 1 liter (which is 1000 mL) of the syrup: \( \text{Mass} = 1.06 \, \frac{\text{g}}{\text{mL}} \times 1000 \, \text{mL} = 1060 \, \text{g} \).

This calculation is crucial because it helps us understand how much sugar and water are in the solution's mass. Knowing the density allows us to move between volume and mass with ease, which is essential when dealing with solution concentrations in chemistry.
mass percentage
Mass percentage is a way to express the concentration of a solute in a solution. It is given by the formula: \( \text{Mass percentage} = \frac{\text{mass of solute}}{\text{total mass of solution}} \times 100 \).

In this problem, the sugar syrup contains 15% sugar by mass. Given the total mass of the solution (1060 g), we calculated the mass of sugar: \( \text{Mass of sugar} = 0.15 \times 1060 \, \text{g} = 159 \, \text{g} \).

Knowing the mass percentage allows us to determine the mass of the solute directly related to the total mass of the solution, giving a clear picture of the composition of the solution.
molar mass
Molar mass is the mass of one mole of a substance. It is expressed in grams per mole (g/mol). To calculate the molar mass of a compound, you sum up the atomic masses of all the atoms in the molecule.

For sugar (\(\mathrm{C}_{12}\mathrm{H}_{22}\mathrm{O}_{11}\)), the molar mass is calculated as follows: \( 12 \times 12.01 + 22 \times 1.01 + 11 \times 16.00 = 342.34 \, \text{g/mol} \).

In the problem, we used this molar mass to convert the given mass of sugar (159 g) into moles: \( \text{Moles of sugar} = \frac{159 \, \text{g}}{342.34 \, \text{g/mol}} \approx 0.464 \, \text{mol} \).

Understanding molar mass is crucial for converting between mass and moles, which is fundamental in stoichiometry and solution concentration calculations.

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Most popular questions from this chapter

Gingerone, a molecule found in ginger, is converted to zingerone by cooking. This is the molecule that contributes the flavor to foods cooked with ginger. You are perfecting the recipe for your punch and have discovered that to achieve the perfect flavor you need to have a final concentration of zingerone of \(6.05 \times 10^{-5} M\). How much of a \(1.15 \times 10^{-3} M\) solution of zingerone do you need to make \(10.0\) liters of punch?

A solution of \(5.36 \mathrm{~g}\) of a molecular compound dissolved in \(76.8 \mathrm{~g}\) benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\) has a boiling point of \(81.48^{\circ} \mathrm{C}\). What is the molar mass of the compound? Boiling point for benzene \(=80.1^{\circ} \mathrm{C}\) \(K_{b}\) for benzene \(=2.53^{\circ} \mathrm{C} \mathrm{kg}\) solvent \(/ \mathrm{mol}\) solute

What happens to sugar molecules \(\left(\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}\right)\) when they are dissolved in water?

Use the equation to calculate the following: \(2 \mathrm{NaOH}(a q)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{Na}_{2} \mathrm{SO}_{4}(a q)+2 \mathrm{H}_{2} \mathrm{O}(l)\) (a) the moles of \(\mathrm{Na}_{2} \mathrm{SO}_{4}\) produced from \(3.6 \mathrm{~mol} \mathrm{H} \mathrm{H}_{2} \mathrm{SO}_{4}\) (b) the moles of \(\mathrm{H}_{2} \mathrm{O}\) produced from \(0.025 \mathrm{~mol} \mathrm{NaOH}\) (c) the moles of \(\mathrm{NaOH}\) required to react with \(2.50 \mathrm{~L}\) of \(0.125 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) (d) the grams of \(\mathrm{Na}_{2} \mathrm{SO}_{4}\) that can be obtained from \(25 \mathrm{~mL}\) of \(0.050 \mathrm{M} \mathrm{NaOH}\) (e) the volume of \(0.250 \mathrm{MH}_{2} \mathrm{SO}_{4}\) needed to react with \(25.5 \mathrm{~mL}\) of \(0.750 \mathrm{M} \mathrm{NaOH}\) (f) the molarity \((M)\) of the \(\mathrm{NaOH}\) solution when \(48.20 \mathrm{~mL}\) react with \(35.72 \mathrm{~mL}\) of \(0.125 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\)

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