Chapter 15: Problem 63
If \(380 \mathrm{~mL}\) of \(0.35 \mathrm{M} \mathrm{Ba}(\mathrm{OH})_{2}\) are added to 500 . \(\mathrm{mL}\) of \(0.65\) \(M \mathrm{HCl}\), will the mixture be acidic or basic? Find the \(\mathrm{pH}\) of the resulting solution.
Short Answer
Expert verified
The solution is acidic with a pH of approximately 1.17.
Step by step solution
01
- Determine moles of \(\text{Ba(OH)}_2\)
Calculate the moles of \(\text{Ba(OH)}_2\) using the formula \(\text{moles} = \text{Molarity} \times \text{Volume}\). With \(\text{Molarity} = 0.35 \text{M}\) and \(\text{Volume} = 380 \text{mL} = 0.380 \text{L}\), we get: \[ \text{moles of } \text{Ba(OH)}_2 = 0.35 \text{M} \times 0.380 \text{L} = 0.133 \text{moles} \] Since \(\text{Ba(OH)}_2\) dissociates completely to provide 2 moles of \(\text{OH}^-\) per mole of \(\text{Ba(OH)}_2\), \[ \text{moles of } \text{OH}^- = 2 \times 0.133 = 0.266 \text{moles} \]
02
- Determine moles of HCl
Calculate the moles of \(\text{HCl}\) using the formula \(\text{moles} = \text{Molarity} \times \text{Volume}\). With \(\text{Molarity} = 0.65 \text{M}\) and \(\text{Volume} = 500 \text{mL} = 0.500 \text{L}\), we get: \[ \text{moles of } \text{HCl} = 0.65 \text{M} \times 0.500 \text{L} = 0.325 \text{moles} \]
03
- Determine limiting reagent
Comparing moles of \(\text{OH}^-\) and \(\text{HCl}\), we can see that \(\text{OH}^-\) is less: \(\text{OH}^- = 0.266 \text{moles}\) and \(\text{HCl} = 0.325 \text{moles}\). Therefore, \(\text{OH}^-\) will completely react with \(\text{HCl}\). \[ \text{moles of } \text{HCl remaining} = 0.325 - 0.266 = 0.059 \text{moles} \]
04
- Determine the concentration of remaining HCl in the mixture
The total volume of the solution after mixing is: \[ \text{Volume total} = 500 \text{mL} + 380 \text{mL} = 880 \text{mL} = 0.880 \text{L} \] Therefore, the concentration of \(\text{H}^+\) ions (from \(\text{HCl}\)) is: \[ \text{Concentration of } \text{H}^+ = \frac{0.059 \text{moles}}{0.880 \text{L}} = 0.067 \text{M} \]
05
- Calculate the pH
The \(\text{pH}\) is calculated by taking the negative logarithm of the \( \text{H}^+ \) concentration: \[ \text{pH} = - \text{log}(0.067) \approx 1.17 \]
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Molarity
When working with solutions in chemistry, molarity is a crucial concept. Molarity (M) refers to the concentration of a solution. It is defined as the number of moles of solute (the substance being dissolved) per liter of solution. The formula to determine molarity is simple: \[ \text{Molarity (M)} = \frac{\text{moles of solute}}{\text{volume of solution in liters}} \]
For instance, in the original exercise, we had a solution of \text{Ba(OH)}_2 with a molarity of 0.35 M and a volume of 380 mL (which is 0.380 L). By multiplying these values, we found the number of moles of \text{Ba(OH)}_2. Remember to always convert the volume into liters before calculating molarity.
This simple concept allows us to quantify how strong a solution is and is often the first step in solving many chemistry problems.
For instance, in the original exercise, we had a solution of \text{Ba(OH)}_2 with a molarity of 0.35 M and a volume of 380 mL (which is 0.380 L). By multiplying these values, we found the number of moles of \text{Ba(OH)}_2. Remember to always convert the volume into liters before calculating molarity.
This simple concept allows us to quantify how strong a solution is and is often the first step in solving many chemistry problems.
Limiting Reagent
In any chemical reaction, the limiting reagent is the substance that gets completely consumed first and thus determines the maximum amount of product that can be formed. Identifying the limiting reagent involves comparing the mole ratios of the reactants based on the balanced chemical equation.
In our example, we were dealing with \text{Ba(OH)}_2 and \text{HCl} in an acid-base reaction. By calculating the moles of each reactant, we determined that \text{OH}^- (from \text{Ba(OH)}_2) was the limiting reagent because it had fewer moles compared to \text{HCl}. \[ \text{moles of } \text{OH}^- = 0.266 \text{ and } \text{moles of } \text{HCl} = 0.325 \]
With the limiting reagent fully reacting, the remaining excess of the second reagent can be calculated to understand the reaction's outcome further.
In our example, we were dealing with \text{Ba(OH)}_2 and \text{HCl} in an acid-base reaction. By calculating the moles of each reactant, we determined that \text{OH}^- (from \text{Ba(OH)}_2) was the limiting reagent because it had fewer moles compared to \text{HCl}. \[ \text{moles of } \text{OH}^- = 0.266 \text{ and } \text{moles of } \text{HCl} = 0.325 \]
With the limiting reagent fully reacting, the remaining excess of the second reagent can be calculated to understand the reaction's outcome further.
Acid-Base Reactions
Acid-base reactions are common in chemistry and involve the transfer of protons (H+ ions) from the acid to the base. In aqueous solutions:
The resulting mixture still contained an excess of \text{HCl}, which kept the solution acidic. Knowing the remaining moles of \text{HCl} helped in calculating the final concentration of H+ ions, leading to the determination of pH.
- Acids release H+ ions (protons).
- Bases release OH- (hydroxide) ions.
The resulting mixture still contained an excess of \text{HCl}, which kept the solution acidic. Knowing the remaining moles of \text{HCl} helped in calculating the final concentration of H+ ions, leading to the determination of pH.
Logarithms
In chemistry, logarithms are frequently used to describe the concentrations of hydronium ions (H+) in a solution. pH is a logarithmic scale used to specify the acidity or basicity of an aqueous solution, defined as: \[ \text{pH} = - \text{log}[\text{H}^+] \]
Here, \text{log} refers to the base-10 logarithm. A decrease in one pH unit corresponds to a tenfold increase in H+ ion concentration.
In our problem, once we calculated the H+ concentration from the remaining HCl as 0.067 M, we found the pH using the logarithm: \[ \text{pH} = - \text{log}(0.067) \]
This gives us a pH of approximately 1.17, indicating a strongly acidic solution. Understanding how to manipulate and interpret logarithms is essential in accurately determining pH values in chemistry.
Here, \text{log} refers to the base-10 logarithm. A decrease in one pH unit corresponds to a tenfold increase in H+ ion concentration.
In our problem, once we calculated the H+ concentration from the remaining HCl as 0.067 M, we found the pH using the logarithm: \[ \text{pH} = - \text{log}(0.067) \]
This gives us a pH of approximately 1.17, indicating a strongly acidic solution. Understanding how to manipulate and interpret logarithms is essential in accurately determining pH values in chemistry.