Chapter 19: Problem 79
Give the common and IUPAC names for the first five straightchain carboxylic acids.
Short Answer
Expert verified
Methanoic Acid (Formic Acid), Ethanoic Acid (Acetic Acid), Propanoic Acid (Propionic Acid), Butanoic Acid (Butyric Acid), Pentanoic Acid (Valeric Acid).
Step by step solution
01
- Identify the Structure of Carboxylic Acids
Understand that carboxylic acids have the functional group COOH, with a carbon (C) atom double-bonded to an oxygen (O) atom and also bonded to a hydroxyl group (-OH). Straight-chain carboxylic acids have no branches in their carbon chain.
02
- Name the First Carboxylic Acid
Methanoic Acid (Common name: Formic Acid) - It has one carbon atom in the chain.
03
- Name the Second Carboxylic Acid
Ethanoic Acid (Common name: Acetic Acid) - It has two carbon atoms in the chain.
04
- Name the Third Carboxylic Acid
Propanoic Acid (Common name: Propionic Acid) - It has three carbon atoms in the chain.
05
- Name the Fourth Carboxylic Acid
Butanoic Acid (Common name: Butyric Acid) - It has four carbon atoms in the chain.
06
- Name the Fifth Carboxylic Acid
Pentanoic Acid (Common name: Valeric Acid) - It has five carbon atoms in the chain.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Organic Chemistry
Organic chemistry is a vibrant and dynamic field of chemistry that focuses on the study of carbon-containing compounds, which can range from simple molecules like methane to complex structures such as DNA. In this branch of chemistry, scientists explore the ways in which carbon atoms bond together, and with other elements like hydrogen, oxygen, and nitrogen. With its diverse array of compounds, organic chemistry is pertinent to life sciences and industries including pharmaceuticals, petrochemicals, and polymers. The discipline is grounded in understanding the properties and reactions of organic molecules, which can vary markedly depending on their structure and functional groups.
Carboxylic Acid Functional Group
A functional group in organic chemistry refers to specific groups of atoms within molecules that are responsible for the characteristic chemical reactions of those molecules. The carboxylic acid functional group is one such group, distinguished by its structure, which includes a carbonyl (a carbon atom double-bonded to an oxygen atom) and a hydroxyl group (a bond between an oxygen atom and a hydrogen atom) connected to the same carbon.The formula for this functional group is COOH or R-COOH, where 'R' represents the remaining carbon chain or ring. This group's properties imbue the carboxylic acids with their acidic nature because the hydroxyl hydrogen is acidic and can dissociate in aqueous solutions.
IUPAC Nomenclature
The International Union of Pure and Applied Chemistry (IUPAC) nomenclature system is a standardized method for naming chemical compounds. The goal is to ensure that each compound has a unique and universally understood name. In the case of carboxylic acids, the IUPAC name is derived by identifying the longest carbon chain that includes the carboxyl functional group, and then replacing the '-e' ending of the corresponding alkane with '-oic acid'. For example, a one-carbon chain with a carboxylic acid is named 'methanoic acid', while a two-carbon chain would be 'ethanoic acid'. Understanding the IUPAC naming system is crucial for students of organic chemistry as it forms the basis for communication within the scientific community.
Straight-Chain Carboxylic Acids
Straight-chain carboxylic acids are a class of carboxylic acids in which the carbon atoms form a continuous, unbranched chain. This linear structure is significant because it influences the properties and reactions of these acids. The simplest straight-chain carboxylic acid is methanoic acid, or formic acid, which has a single carbon. As the chain length increases, the common names and IUPAC names start to differ. Here's a quick reference list for the first five straight-chain carboxylic acids:
- Methanoic Acid (Common name: Formic Acid)
- Ethanoic Acid (Common name: Acetic Acid)
- Propanoic Acid (Common name: Propionic Acid)
- Butanoic Acid (Common name: Butyric Acid)
- Pentanoic Acid (Common name: Valeric Acid)