. For each of the following compounds, indicate what is wrong with the name and why. If possible, fix the name. (a) iron hydroxide (b) dipotassium dichromium heptoxide (c) sulfur oxide

Short Answer

Expert verified
Correct names: iron(II/III) hydroxide, potassium dichromate, sulfur dioxide/trioxide.

Step by step solution

01

Analyze the Name of Iron Hydroxide

The name 'iron hydroxide' is incomplete because it does not indicate the oxidation state of iron. Iron can have multiple oxidation states, such as +2 or +3.
02

Fix the Name of Iron Hydroxide

To correctly name iron hydroxide, include the oxidation state of iron. For Fe(OH)_2, the name should be 'iron(II) hydroxide', and for Fe(OH)_3, it should be 'iron(III) hydroxide.'
03

Analyze the Name of Dipotassium Dichromium Heptoxide

The name 'dipotassium dichromium heptoxide' is incorrect because it does not follow the standard naming convention for this type of compound. The compound likely intended is K2Cr2O7.
04

Fix the Name of Dipotassium Dichromium Heptoxide

The correct name for K2Cr2O7 is 'potassium dichromate'. 'Dichromate' signifies the Cr2O7 anion, and 'potassium' indicates the K+ cations.
05

Analyze the Name of Sulfur Oxide

The name 'sulfur oxide' is vague because sulfur forms multiple oxides with different stoichiometries, such as SO2 and SO3.
06

Fix the Name of Sulfur Oxide

Specify which oxide of sulfur it is. For SO2, the correct name is 'sulfur dioxide'; for SO3, the correct name is 'sulfur trioxide'.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Oxidation States
Oxidation states refer to the charge of an atom within a molecule. They're crucial for properly naming chemical compounds and understanding their reactions. In chemical nomenclature, especially for transition metals like iron, indicating the oxidation state helps specify which form of the element is present. For example, iron can exist in +2 and +3 oxidation states. The compound Fe(OH)_2 should be named 'iron(II) hydroxide' because iron is in a +2 state, and Fe(OH)_3 should be 'iron(III) hydroxide' for iron in the +3 state.
Always include oxidation states in the name to avoid ambiguity.
This practice is essential for compounds with elements that can have multiple oxidation states.
  • Fe(OH)_2: iron(II) hydroxide
  • Fe(OH)_3: iron(III) hydroxide
Chemical Nomenclature
Chemical nomenclature is the systematic naming of chemical compounds according to agreed conventions. It's vital for clear communication in chemistry.
Names provide essential details about the structure and composition of the compound. For instance, in the name 'potassium dichromate', 'potassium' indicates the presence of K+ ions, and 'dichromate' refers to the Cr2O7^2- anion.
This nomination method ensures universal understanding.
Another example is correcting 'dipotassium dichromium heptoxide' to 'potassium dichromate' which follows the standard conventions.
Using proper naming methods avoids confusion and ensures precise identification of compounds.
  • K2Cr2O7: potassium dichromate
Common Compounds
Common compounds have widely accepted and recognizable names that follow standard naming rules. For these compounds, precise naming removes ambiguity and clarifies the specific form.
Sulfur can form multiple oxides. 'Sulfur oxide' is ambiguous, while 'sulfur dioxide' (SO2) and 'sulfur trioxide' (SO3) are clear and specific.
Common compound names also reflect their stoichiometry, providing insight into their chemical behavior.
For example:
  • SO2: sulfur dioxide
  • SO3: sulfur trioxide
Using standardized names not only aids in learning but also in understanding chemical interactions and properties.
Transition Metals
Transition metals are elements found in the d-block of the periodic table. They are known for their various oxidation states and complex chemistry.
This variability in oxidation states necessitates including state-specific details in their names.
Misleading names like 'iron hydroxide' should be corrected to 'iron(II) hydroxide' or 'iron(III) hydroxide' depending on the state.
Transition metals often form complex ions and colorful compounds.
Understanding their naming conventions is essential for studying their reactions and properties.
Common transition metals include iron (Fe), copper (Cu), and chromium (Cr). Correct nomenclature for these metals ensures clarity and precision in chemical communication.
  • Fe: Iron(II) hydroxide = Fe(OH)_2, Iron(III) hydroxide = Fe(OH)_3
  • Cu: Copper(I) oxide = Cu2O, Copper(II) oxide = CuO
  • Cr: Chromium(III) oxide = Cr2O3, Chromium(VI) oxide = CrO3

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