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Chapter 10: Problem 137
Which molecule is nonpolar? (a) \(\mathrm{SO}_{3} ;\) (b) \(\mathrm{CH}_{2} \mathrm{Cl}_{2}\); (c) \(\mathrm{NH}_{3} ;\) (d) FNO.
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Draw three resonance structures for the sulfine molecule, \(\mathrm{H}_{2} \mathrm{CSO}\). Do not consider ring structures.
Estimate the lengths of the following bonds and indicate whether your estimate is likely to be too high or too low: (a) I \(-\mathrm{Cl} ;\) (b) \(\mathrm{C}-\mathrm{F}\).
Each of the following molecules contains one or more multiple covalent bonds. Draw plausible Lewis structures to represent this fact, and predict the shape of each molecule. (a) \(\mathrm{CO}_{2} ;\) (b) \(\mathrm{Cl}_{2} \mathrm{CO} ;\) (c) CINO \(_{2}\).
Draw a plausible Lewis structure for the following series of molecules and ions: (a) \(\mathrm{ClF}_{2}^{-} ;\) (b) \(\mathrm{ClF}_{3}\); (c) \(\mathrm{ClF}_{4}^{-} ;\) (d) ClF \(_{5} .\) Describe the electron group geometry and molecular structure of these species.
One of the isomers of chloromethanol has the formula $\mathrm{ClCH}_{2} \mathrm{OH} .$ Sketch, by using the dash and wedge symbolism, this isomer of chloromethanol, and indicate the various bond angles.
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